Mechanisms of Sulfoxidation and Epoxidation Mediated by Iron(III)-Iodosylbenzene Adduct: Electron-Transfer vs. Oxygen-Transfer Mechanism

The mechanisms of sulfoxidation and epoxidation mediated by previously synthesized and characterized iron(III)-iodosylbenzene adduct, Fe<sup>III</sup>(OIPh) were investigated using para-substituted thioanisole and styrene derivatives as model substrates. Based on detailed kinetic reactio...

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Bibliographic Details
Published in:	Molecules
Main Authors:	Patrik Török, Dóra Lakk-Bogáth, József Kaizer
Format:	Article
Language:	English
Published:	MDPI AG 2023-06-01
Subjects:	non-heme models iron(III)-iodosylarene complex sulfoxidation epoxidation O-atom transfer kinetics
Online Access:	https://www.mdpi.com/1420-3049/28/12/4745

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