A comparative study of the Au-catalyzed cyclization of hydroxy-substituted allylic alcohols and ethers

The Au(I)-catalyzed cyclization of hydroxyallylic ethers to form tetrahydropyrans is reported. Employing (acetonitrile)[(o-biphenyl)di-tert-butylphosphine]gold(I) hexafluoroantimonate, the cyclization reactions were complete within minutes to hours, depending on the substrate. The reaction progress...

وصف كامل

التفاصيل البيبلوغرافية
الحاوية / القاعدة:Beilstein Journal of Organic Chemistry
المؤلفون الرئيسيون: Berenger Biannic, Thomas Ghebreghiorgis, Aaron Aponick
التنسيق: مقال
اللغة:الإنجليزية
منشور في: Beilstein-Institut 2011-06-01
الموضوعات:
الوصول للمادة أونلاين:https://doi.org/10.3762/bjoc.7.91