A study on the allylic oxidation of some β-rose ketones

A study on the allylic oxidation of β-rose ketones was conducted. The oxo-derivatives of three representative rose ketones β-damascone, β-damascenone and β-ionone were synthesized by using Rh-catalyzed allylic oxidation in good yields at room temperature in the presence of tert-butyl hydroperoxide....

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Bibliographic Details
Published in:Results in Chemistry
Main Authors: Deshou Mao, Shihua Zhu, Yafen Zhao, Wenwen Zhang, Ruilin Hu, Bingbiao Cai, Cenming Zhu, Ankun Zhou, Jianfeng Li
Format: Article
Language:English
Published: Elsevier 2025-07-01
Subjects:
Rose ketones
4-oxo-β-damascone
6-oxo-β-damascenone
4-oxo-ionone
Rhodium catalysis
Allylic oxidation
Online Access:http://www.sciencedirect.com/science/article/pii/S2211715625004278

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http://www.sciencedirect.com/science/article/pii/S2211715625004278

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