Beckmann Rearrangement of Ketoximes Induced by Phenyl Dichlorophosphate at Ambient Temperature

Upon treatment with phenyl dichlorophosphate (PhOP=OCl2) in acetonitrile at ambient temperature, a variety of ketoximes underwent a Beckmann rearrangement in an effective manner to afford the corresponding amides in moderate to high yields.

Bibliographic Details
Published in:Molecules
Main Authors: Ching-Fa Yao, Kak-Shan Shia, Yi-Ming Shao, Shijay Gao, Chun-Wei Kuo, Min-Tsang Hsieh
Format: Article
Language:English
Published: MDPI AG 2012-11-01
Subjects:
Beckmann rearrangement
phenyl dichlorophosphate
ketoximes
ambient temperature
Online Access:http://www.mdpi.com/1420-3049/17/11/13662

Internet

http://www.mdpi.com/1420-3049/17/11/13662

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