SYNTHESIS OF THREE NEW BIFUNCTIONAL GLUCOSE-THIOUREA ORGANOCATALYSTS AND THEIR APPLICATION IN ASYMMETRIC MICHAEL ADDITION

Three new glucose-based asymmetric bifunctional organocatalysts containing a 6-aminopyridyl or a 6-methylpyridyl or a cinchona unit were synthesized. Asymmetric Michael addition of pentane-2,4-dione to β-nitrostyrene was catalyzed successfully by these catalysts. In case of the cinchona based gluco...

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Bibliographic Details

Published in:	Studia Universitatis Babes-Bolyai Chemia
Main Authors:	Sándor NAGY, Petra KOZMA, Péter KISSZÉKELYI, Dóra BEZZEGH, Péter HUSZTHY, József KUPAI
Format:	Article
Language:	English
Published:	Babes-Bolyai University 2017-03-01
Subjects:	organocatalyst, carbohydrates, cinchona alkaloids, Michael addition, asymmetric syntheses
Online Access:	https://studia.reviste.ubbcluj.ro/index.php/chemia/article/view/8266