Magnetocaloric effect in a high-spin ferromagnetic molecular cluster

The reaction of MnCl2·4H2O with HL ((1-methyl-1H-imidazol-2-yl)methanol) and pdH2 (1, 3 propanediol) in a basic MeCN solution results in the formation of a mixed-valence [Mn20] cationic cluster and two [MnIICl4] counter anions. The metallic skeleton of the cluster describes two geometrically equival...

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Bibliographic Details

Published in:	Frontiers in Chemistry
Main Authors:	Eleftheria Agapaki, Emmanouil K. Charkiolakis, Gary S. Nichol, David Gracia, Marco Evangelisti, Euan K. Brechin
Format:	Article
Language:	English
Published:	Frontiers Media S.A. 2024-10-01
Subjects:	cluster compounds magnetic properties ferromagnetism magnetocaloric effect manganese
Online Access:	https://www.frontiersin.org/articles/10.3389/fchem.2024.1494609/full