Azo group-enabled metal- and oxidant-free alkenyl C–H thiolation: Access to stereodefined tetrasubstituted acyclic olefins

Metal- and oxidant-free alkenyl C–H thiolation enabled by the azo group had been established for the modular synthesis of tetrasubstituted acyclic olefins. The reaction was performed under mild reaction conditions with a broad substrate scope. The intramolecular 6-membered hydrogen-bonding network a...

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Bibliographic Details

Published in:	Green Synthesis and Catalysis
Main Authors:	Hao-Jie Gao, Yu-Hang Miao, Shi-Kun Jia, Na Li, Li-Ping Xu, Wei Wang, Min-Can Wang, Guang-Jian Mei
Format:	Article
Language:	English
Published:	KeAi Communications Co. Ltd. 2023-02-01
Subjects:	Tetrasubstituted acyclic olefins Azo group C–H thiolation Metal-free
Online Access:	http://www.sciencedirect.com/science/article/pii/S2666554922000941