Synthesis of Catena-bis(μ-bromo)-(<i>O</i>-methyl-<i>N</i>-phenylthiocarbamate)-dicopper(I) and Its Reactivity towards PAr₃ (Ar = Ph, <i>p</i>-Tol)

In order to investigate the coordination chemistry of <i>O</i>-alkyl <i>N</i>-aryl thiocarbamate ligands toward coinage metals, CuBr was reacted with one equivalent of MeOC(=S)N(H)Ph <b>L</b> in MeCN solution to afford the 1D-polymeric title compound [{Cu(<i>...

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Bibliographic Details

Published in:	Molbank
Main Authors:	Wafa Arar, Lydie Viau, Isabelle Jourdain, Michael Knorr, Carsten Strohmann, Rebecca Scheel, Azaiez Ben Akacha
Format:	Article
Language:	English
Published:	MDPI AG 2023-05-01
Subjects:	copper bromide thiocarbamate thione crystal structure hydrogen bonding aryl phosphine
Online Access:	https://www.mdpi.com/1422-8599/2023/2/M1655