Unanticipated switch of reactivity of isonitrile via N≡C bond scission: Cascade formation of symmetrical sulfonyl guanidine

Summary: Unanticipated formation of symmetrical sulfonyl guanidine was observed while treating isonitriles with N,N-dibromoarylsulfonamides in absence of an external amine source. Interesting feature of this work is that one molecule of isonitrile initially reacts with dibromoarylsulfonamide via the...

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Bibliographic Details

Published in:	iScience
Main Authors:	Debashish Mishra, Sagarika Rajkhowa, Prodeep Phukan
Format:	Article
Language:	English
Published:	Elsevier 2023-08-01
Subjects:	Chemistry Organic chemistry Organic reaction
Online Access:	http://www.sciencedirect.com/science/article/pii/S2589004223013354