Spontaneous FeIII/FeII redox cycling in single-atom catalysts: Conjugation effect and electron delocalization

Summary: The mechanism of spontaneous FeIII/FeII redox cycling in iron-centered single-atom catalysts (I-SACs) is often overlooked. Consequently, pathways for continuous SO4·-/HO⋅ generation during peroxymonosulfate (PMS) activation by I-SACs remain unclear. Herein, the evolution of the iron center...

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Bibliographic Details

Published in:	iScience
Main Authors:	Zheng Qian, Lingzhen Wang, Mawuli Dzakpasu, Yujia Tian, Dahu Ding, Rongzhi Chen, Gen Wang, Shengjiong Yang
Format:	Article
Language:	English
Published:	Elsevier 2023-01-01
Subjects:	Chemistry Catalysis Materials science Materials chemistry
Online Access:	http://www.sciencedirect.com/science/article/pii/S2589004222021757