Preparation of T8 and double-decker silsesquioxane-based Janus-type molecules: molecular modeling and DFT insights

Abstract We present a methodology for the synthesis of inorganic-organic Janus-type molecules based on mono-T8 and difunctionalized double-decker silsesquioxanes (DDSQs) via hydrosilylation reactions, achieving exceptionally high yields and selectivities. The synthesized compounds were extensively c...

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Bibliographic Details
Published in:Scientific Reports
Main Authors: Julia Duszczak-Kaczmarek, Katarzyna Mituła-Chmielowiec, Monika Rzonsowska, Wojciech Jankowski, Marcin Hoffmann, Jędrzej Walkowiak, Beata Dudziec
Format: Article
Language:English
Published: Nature Portfolio 2024-08-01
Subjects:
Silsesquioxane
DDSQ
Janus compounds
Catalysis
Hydrosilylation
Molecular modeling
Online Access:https://doi.org/10.1038/s41598-024-69481-6

Internet

https://doi.org/10.1038/s41598-024-69481-6

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