Hierarchically assembled helicates as reaction platform – from stoichiometric Diels–Alder reactions to enamine catalysis

The stereoselectivity of a Diels–Alder reaction within the periphery of hierarchically assembled titanium(IV) helicates formed from mixtures of achiral, reactive and chiral, unreactive ligands was investigated in detail. Following the pathway of the chiral induction, the chiral ligands, solvents as...

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Bibliographic Details

Published in:	Beilstein Journal of Organic Chemistry
Main Authors:	David Van Craen, Jenny Begall, Johannes Großkurth, Leonard Himmel, Oliver Linnenberg, Elisabeth Isaak, Markus Albrecht
Format:	Article
Language:	English
Published:	Beilstein-Institut 2020-09-01
Subjects:	diels–alder reaction enamine catalysis hierarchical helicates remote-control stereoselectivity
Online Access:	https://doi.org/10.3762/bjoc.16.195