Chiroptical Properties and the Racemization of Pyrene and Tetrathiafulvalene-Substituted Allene: Substitution and Solvent Effects on Racemization in Tetrathiafulvalenylallene

Dissymmetric 1,3-diphenylallene derivative 3 connected with 4,5-bis(methyl-thio)tetrathiafulvalenyl and 1-pyrenyl substituents was prepared and characterized. The molecular structure was determined by X-ray crystallographic analysis. Optical resolution was accomplished using a recycling chiral HPLC,...

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Bibliographic Details

Published in:	Molecules
Main Authors:	Masashi Hasegawa, Seiya Iwata, Yasuto Sone, Junta Endo, Hideyo Matsuzawa, Yasuhiro Mazaki
Format:	Article
Language:	English
Published:	MDPI AG 2014-03-01
Subjects:	axis chirality allene tetrathiafulvalene electronic circular dichroism racemization
Online Access:	http://www.mdpi.com/1420-3049/19/3/2829