Syntheses of Au(III) and Au(I) Complexes of 3,4,5,6-Tetraphenyl-2,2´-bipyridine

Treatment of the ligand 3,4,5,6-tetraphenyl-2,2´-bipyridine (LH) VIII with HAuCl4 in acetonitrile afforded the cyclometallated square-planar Au(III) complex [LAuCl]ClO4 (7) containing the anionic tridentate (N∧N∧C) ligand, via orthometallation. Treatment of (7) with 4-dimetylaminopyridine (DMAP)...

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Bibliographic Details

Published in:	OUSL Journal
Main Author:	Sarath D. Perera
Format:	Article
Language:	English
Published:	The Open University of Sri Lanka 2023-09-01
Subjects:	gold au(iii)/au(i) complexes cyclometallation bipyridine (n∧n) and (n∧n∧c) ligands
Online Access:	https://storage.googleapis.com/jnl-sljo-j-ouslj-files/journals/1/articles/7600/64f956d687ca4.pdf