1,2,5,10,11,14-Hexaoxadispiro[5.2.5.2]hexadecanes: Novel Spirofused Bis-Trioxane Peroxides

A set of new bis-spirofused 1,2,4-trioxanes 4a-d was obtained from the reaction of cyclohexane-1,4-dione with allylic hydroperoxides 2a-d, bearing an additional hydroxy group in the homoallylic position, by diastereoselective photooxygenation of allylic alcohols 1a-d and subsequent BF3-catalyzed per...

Full description

Bibliographic Details

Published in:	Molecules
Main Authors:	Tamer T. El-Idreesy, Dirk Blunk, Jörg Neudörfl, Johann Lex, Lars-Oliver Höinck, Axel G. Griesbeck
Format:	Article
Language:	English
Published:	MDPI AG 2008-08-01
Subjects:	Bis-spiro compounds peroxides singlet oxygen DFT calculations X-ray structure determination.
Online Access:	http://www.mdpi.com/1420-3049/13/8/1743/