<i>N</i>,<i>N</i>′-Diaryldihydrophenazines as a Sustainable and Cost-Effective Alternative to Precious Metal Complexes in the Photoredox-Catalyzed Alkylation of Aryl Alkyl Ketones

An inexpensive and highly efficient metal-free alternative to commonly used Ru- and Ir-based catalysts was proposed. It was shown that the new 2,7-di-<i>tert</i>-butyl-5,10-bis(4-trifluoromethylphenyl)-5,10-dihydrophenazine outcompeted the iridium phenylpyridyl complex in photoredox acti...

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发表在:	Molecules
Main Authors:	Dmitry A. Dulov, Alexey V. Bogdanov, Sergey G. Dorofeev, Tatiana V. Magdesieva
格式:	文件
语言:	英语
出版:	MDPI AG 2022-12-01
主题:	diaryldihydraphenazines photoredox catalysis thermally activated delayed fluorescence triplet state ESR quantum chemical calculations
在线阅读:	https://www.mdpi.com/1420-3049/28/1/221