Halogen Substituent Effect on the Spin-Transition Temperature in Spin-Crossover Fe(III) Compounds Bearing Salicylaldehyde 2-Pyridyl Hydrazone-Type Ligands and Dicarboxylic Acids

Four Fe(III) spin-crossover (SCO) compounds, [Fe(HL1)2](HCl4TPA) (1-Cl), [Fe(HL1)2](HBr4TPA) (1-Br), [Fe(HL2)2](HCl4TPA) (2-Cl), and [Fe(HL2)2](HBr4TPA) (2-Br) (HL1 = 4-chloro-2-nitro-6-(1-(2-(pyridine-2-yl)hydrazono)ethyl)phenolate; HL2 = 4-bromo-2-nitro-6-(1-(2-(pyridine-2-yl)hydrazono)ethyl)pheno...

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書誌詳細

出版年:	Inorganics
主要な著者:	Takumi Nakanishi, Atsushi Okazawa, Osamu Sato
フォーマット:	論文
言語:	英語
出版事項:	MDPI AG 2017-08-01
主題:	spin crossover hydrazone complex dicarboxylic acid
オンライン･アクセス:	https://www.mdpi.com/2304-6740/5/3/53