Design and synthesis of palladium (II) OCO pincer type complexes and their catalytic role towards the α-arylation of ketones
Twelve OCO bisacetamide ligands 4aa-4dc were synthesized after condensation of isophenylenediamines 1a-1d and anhydride/acyl chlorides. The corresponding Pd(II)–OCO–H(5aa-5ac), Pd(II)–OCO–Me(5ba-5bc), Pd(II)–OCO–OMe(5ca-5 cc), Pd(II)–OCO–NO2(5da-5dc) pincer complexes were prepared via C-H activation...
| Published in: | Journal of Saudi Chemical Society |
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| Main Authors: | , , , |
| Format: | Article |
| Language: | English |
| Published: |
Springer
2019-03-01
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| Online Access: | http://www.sciencedirect.com/science/article/pii/S131961031830084X |