Design and synthesis of palladium (II) OCO pincer type complexes and their catalytic role towards the α-arylation of ketones
Twelve OCO bisacetamide ligands 4aa-4dc were synthesized after condensation of isophenylenediamines 1a-1d and anhydride/acyl chlorides. The corresponding Pd(II)–OCO–H(5aa-5ac), Pd(II)–OCO–Me(5ba-5bc), Pd(II)–OCO–OMe(5ca-5 cc), Pd(II)–OCO–NO2(5da-5dc) pincer complexes were prepared via C-H activation...
| Published in: | Journal of Saudi Chemical Society |
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| Main Authors: | , , , |
| Format: | Article |
| Language: | English |
| Published: |
Springer
2019-03-01
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| Online Access: | http://www.sciencedirect.com/science/article/pii/S131961031830084X |
| _version_ | 1848652894976344064 |
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| author | Wang Kai Hua Qian Dabin Liu Zhiwen Ye |
| author_facet | Wang Kai Hua Qian Dabin Liu Zhiwen Ye |
| author_sort | Wang Kai |
| collection | DOAJ |
| container_title | Journal of Saudi Chemical Society |
| description | Twelve OCO bisacetamide ligands 4aa-4dc were synthesized after condensation of isophenylenediamines 1a-1d and anhydride/acyl chlorides. The corresponding Pd(II)–OCO–H(5aa-5ac), Pd(II)–OCO–Me(5ba-5bc), Pd(II)–OCO–OMe(5ca-5 cc), Pd(II)–OCO–NO2(5da-5dc) pincer complexes were prepared via C-H activation of precursors and Pd(OAc)2, and characterized by IR, 1H NMR, 13C NMR and elemental analysis. The α-arylation of ketones and aryl bromides catalyzed by 5 under low catalyst loadings (0.1 mol%) show that 5da exhibits the highest catalytic activity, resulting in a 98% isolated yield. Keywords: α-Arylation, Ketones, Aryl halides, Pd-pincer complexes, Catalysis |
| format | Article |
| id | doaj-cab45a83affe4492897e8a595d93bdc2 |
| institution | Directory of Open Access Journals |
| issn | 1319-6103 |
| language | English |
| publishDate | 2019-03-01 |
| publisher | Springer |
| record_format | Article |
| spelling | doaj-cab45a83affe4492897e8a595d93bdc22025-11-02T21:46:18ZengSpringerJournal of Saudi Chemical Society1319-61032019-03-0123327428310.1016/j.jscs.2018.07.004Design and synthesis of palladium (II) OCO pincer type complexes and their catalytic role towards the α-arylation of ketonesWang Kai0Hua Qian1Dabin Liu2Zhiwen Ye3School of Chemical Engineering, Nanjing University of Science and Technology, Jiangsu, Nanjing 210094, ChinaSchool of Chemical Engineering, Nanjing University of Science and Technology, Jiangsu, Nanjing 210094, China; Corresponding author.School of Chemical Engineering, Nanjing University of Science and Technology, Jiangsu, Nanjing 210094, ChinaSchool of Chemical Engineering, Nanjing University of Science and Technology, Jiangsu, Nanjing 210094, ChinaTwelve OCO bisacetamide ligands 4aa-4dc were synthesized after condensation of isophenylenediamines 1a-1d and anhydride/acyl chlorides. The corresponding Pd(II)–OCO–H(5aa-5ac), Pd(II)–OCO–Me(5ba-5bc), Pd(II)–OCO–OMe(5ca-5 cc), Pd(II)–OCO–NO2(5da-5dc) pincer complexes were prepared via C-H activation of precursors and Pd(OAc)2, and characterized by IR, 1H NMR, 13C NMR and elemental analysis. The α-arylation of ketones and aryl bromides catalyzed by 5 under low catalyst loadings (0.1 mol%) show that 5da exhibits the highest catalytic activity, resulting in a 98% isolated yield. Keywords: α-Arylation, Ketones, Aryl halides, Pd-pincer complexes, Catalysishttp://www.sciencedirect.com/science/article/pii/S131961031830084X |
| spellingShingle | Wang Kai Hua Qian Dabin Liu Zhiwen Ye Design and synthesis of palladium (II) OCO pincer type complexes and their catalytic role towards the α-arylation of ketones |
| title | Design and synthesis of palladium (II) OCO pincer type complexes and their catalytic role towards the α-arylation of ketones |
| title_full | Design and synthesis of palladium (II) OCO pincer type complexes and their catalytic role towards the α-arylation of ketones |
| title_fullStr | Design and synthesis of palladium (II) OCO pincer type complexes and their catalytic role towards the α-arylation of ketones |
| title_full_unstemmed | Design and synthesis of palladium (II) OCO pincer type complexes and their catalytic role towards the α-arylation of ketones |
| title_short | Design and synthesis of palladium (II) OCO pincer type complexes and their catalytic role towards the α-arylation of ketones |
| title_sort | design and synthesis of palladium ii oco pincer type complexes and their catalytic role towards the α arylation of ketones |
| url | http://www.sciencedirect.com/science/article/pii/S131961031830084X |
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