Recent Advances in Acyl Suzuki Cross-Coupling

Acyl Suzuki cross-coupling involves the coupling of an organoboron reagent with an acyl electrophile (acyl halide, anhydride, ester, amide). This review provides a timely overview of the very important advances that have recently taken place in the acylative Suzuki cross-coupling. Particular emphasi...

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Bibliographic Details
Main Authors: Jonathan Buchspies, Michal Szostak
Format: Article
Language:English
Published: MDPI AG 2019-01-01
Series:Catalysts
Subjects:
Online Access:http://www.mdpi.com/2073-4344/9/1/53
Description
Summary:Acyl Suzuki cross-coupling involves the coupling of an organoboron reagent with an acyl electrophile (acyl halide, anhydride, ester, amide). This review provides a timely overview of the very important advances that have recently taken place in the acylative Suzuki cross-coupling. Particular emphasis is directed toward the type of acyl electrophiles, catalyst systems and new cross-coupling partners. This review will be of value to synthetic chemists involved in this rapidly developing field of Suzuki cross-coupling as well as those interested in using acylative Suzuki cross-coupling for the synthesis of ketones as a catalytic alternative to stoichiometric nucleophilic additions or Friedel-Crafts reactions.
ISSN:2073-4344