A Selenium-Based Ionic Liquid as a Recyclable Solvent for the Catalyst-Free Synthesis of 3-Selenylindoles

The ionic liquid 1-butyl-3-methylimidazolium methylselenite, [bmim][SeO2(OCH3)], was successfully used as solvent in the catalyst-free preparation of 3-arylselenylindoles by the reaction of indole with ArSeCl at room temperature. The products were obtained selectively in good yields without the need...

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Main Authors: Eder J. Lenardão, Raquel G. Jacob, Samuel R. Mendes, Diego Alves, Gelson Perin, Camilo S. Freitas, Samuel Thurow, Everton G. Zimmermann
Format: Article
Language:English
Published: MDPI AG 2013-04-01
Series:Molecules
Subjects:
Online Access:http://www.mdpi.com/1420-3049/18/4/4081
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spelling doaj-01821cb91a8e4f6ebd055e960d5ba4ab2020-11-24T21:01:25ZengMDPI AGMolecules1420-30492013-04-011844081409010.3390/molecules18044081A Selenium-Based Ionic Liquid as a Recyclable Solvent for the Catalyst-Free Synthesis of 3-SelenylindolesEder J. LenardãoRaquel G. JacobSamuel R. MendesDiego AlvesGelson PerinCamilo S. FreitasSamuel ThurowEverton G. ZimmermannThe ionic liquid 1-butyl-3-methylimidazolium methylselenite, [bmim][SeO2(OCH3)], was successfully used as solvent in the catalyst-free preparation of 3-arylselenylindoles by the reaction of indole with ArSeCl at room temperature. The products were obtained selectively in good yields without the need of any additive and the solvent was easily reused for several cycles with good results.http://www.mdpi.com/1420-3049/18/4/4081selenium ionic liquidselenium compoundsarylselenylindolesindoles
collection DOAJ
language English
format Article
sources DOAJ
author Eder J. Lenardão
Raquel G. Jacob
Samuel R. Mendes
Diego Alves
Gelson Perin
Camilo S. Freitas
Samuel Thurow
Everton G. Zimmermann
spellingShingle Eder J. Lenardão
Raquel G. Jacob
Samuel R. Mendes
Diego Alves
Gelson Perin
Camilo S. Freitas
Samuel Thurow
Everton G. Zimmermann
A Selenium-Based Ionic Liquid as a Recyclable Solvent for the Catalyst-Free Synthesis of 3-Selenylindoles
Molecules
selenium ionic liquid
selenium compounds
arylselenylindoles
indoles
author_facet Eder J. Lenardão
Raquel G. Jacob
Samuel R. Mendes
Diego Alves
Gelson Perin
Camilo S. Freitas
Samuel Thurow
Everton G. Zimmermann
author_sort Eder J. Lenardão
title A Selenium-Based Ionic Liquid as a Recyclable Solvent for the Catalyst-Free Synthesis of 3-Selenylindoles
title_short A Selenium-Based Ionic Liquid as a Recyclable Solvent for the Catalyst-Free Synthesis of 3-Selenylindoles
title_full A Selenium-Based Ionic Liquid as a Recyclable Solvent for the Catalyst-Free Synthesis of 3-Selenylindoles
title_fullStr A Selenium-Based Ionic Liquid as a Recyclable Solvent for the Catalyst-Free Synthesis of 3-Selenylindoles
title_full_unstemmed A Selenium-Based Ionic Liquid as a Recyclable Solvent for the Catalyst-Free Synthesis of 3-Selenylindoles
title_sort selenium-based ionic liquid as a recyclable solvent for the catalyst-free synthesis of 3-selenylindoles
publisher MDPI AG
series Molecules
issn 1420-3049
publishDate 2013-04-01
description The ionic liquid 1-butyl-3-methylimidazolium methylselenite, [bmim][SeO2(OCH3)], was successfully used as solvent in the catalyst-free preparation of 3-arylselenylindoles by the reaction of indole with ArSeCl at room temperature. The products were obtained selectively in good yields without the need of any additive and the solvent was easily reused for several cycles with good results.
topic selenium ionic liquid
selenium compounds
arylselenylindoles
indoles
url http://www.mdpi.com/1420-3049/18/4/4081
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