CH3NH3Cl Assisted Solvent Engineering for Highly Crystallized and Large Grain Size Mixed-Composition (FAPbI3)0.85(MAPbBr3)0.15 Perovskites

CH3NH3Cl Assisted Solvent Engineering for Highly Crystallized and Large Grain Size Mixed-Composition (FAPbI3)0.85(MAPbBr3)0.15 Perovskites

High-quality mixed-cation lead mixed-halide (FAPbI3)0.85(MAPbBr3)0.15 perovskite films have been prepared using CH3NH3Cl additives via the solvent engineering method. The UV/Vis result shows that the addition of additives leads to enhanced absorptions. XRD and SEM characterizations suggest that comp...

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Bibliographic Details
Main Authors: Yihui Li, Taiyang Zhang, Feng Xu, Yong Wang, Ge Li, Yang Yang, Yixin Zhao
Format: Article
Language:English
Published: MDPI AG 2017-09-01
Series:Crystals
Subjects:
perovskite
mixed-cation
mixed-halide
additive
CH3NH3Cl
solvent engineering
Online Access:https://www.mdpi.com/2073-4352/7/9/272
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spelling doaj-01ea058f574f4a108a53aede3e49e37f2020-11-25T02:28:58ZengMDPI AGCrystals2073-43522017-09-017927210.3390/cryst7090272cryst7090272CH3NH3Cl Assisted Solvent Engineering for Highly Crystallized and Large Grain Size Mixed-Composition (FAPbI3)0.85(MAPbBr3)0.15 PerovskitesYihui Li0Taiyang Zhang1Feng Xu2Yong Wang3Ge Li4Yang Yang5Yixin Zhao6School of Environmental Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240, ChinaSchool of Environmental Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240, ChinaSchool of Environmental Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240, ChinaSchool of Environmental Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240, ChinaSchool of Environmental Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240, ChinaClean Energy Research Institute, China Huaneng Group, Beijing 102209, ChinaSchool of Environmental Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240, ChinaHigh-quality mixed-cation lead mixed-halide (FAPbI3)0.85(MAPbBr3)0.15 perovskite films have been prepared using CH3NH3Cl additives via the solvent engineering method. The UV/Vis result shows that the addition of additives leads to enhanced absorptions. XRD and SEM characterizations suggest that compact, pinhole-free and uniform films can be obtained. This is attributable to the crystallization improvement caused by the CH3NH3Cl additives. The power conversion efficiency (PCE) of the F-doped SnO2 (FTO)/compact-TiO2/perovskite/Spiro-OMeTAD/Ag device increases from 15.3% to 16.8% with the help of CH3NH3Cl additive.https://www.mdpi.com/2073-4352/7/9/272perovskitemixed-cationmixed-halideadditiveCH3NH3Clsolvent engineering
collection DOAJ
language English
format Article
sources DOAJ
author Yihui Li
Taiyang Zhang
Feng Xu
Yong Wang
Ge Li
Yang Yang
Yixin Zhao
spellingShingle Yihui Li
Taiyang Zhang
Feng Xu
Yong Wang
Ge Li
Yang Yang
Yixin Zhao
CH3NH3Cl Assisted Solvent Engineering for Highly Crystallized and Large Grain Size Mixed-Composition (FAPbI3)0.85(MAPbBr3)0.15 Perovskites
Crystals
perovskite
mixed-cation
mixed-halide
additive
CH3NH3Cl
solvent engineering
author_facet Yihui Li
Taiyang Zhang
Feng Xu
Yong Wang
Ge Li
Yang Yang
Yixin Zhao
author_sort Yihui Li
title CH3NH3Cl Assisted Solvent Engineering for Highly Crystallized and Large Grain Size Mixed-Composition (FAPbI3)0.85(MAPbBr3)0.15 Perovskites
title_short CH3NH3Cl Assisted Solvent Engineering for Highly Crystallized and Large Grain Size Mixed-Composition (FAPbI3)0.85(MAPbBr3)0.15 Perovskites
title_full CH3NH3Cl Assisted Solvent Engineering for Highly Crystallized and Large Grain Size Mixed-Composition (FAPbI3)0.85(MAPbBr3)0.15 Perovskites
title_fullStr CH3NH3Cl Assisted Solvent Engineering for Highly Crystallized and Large Grain Size Mixed-Composition (FAPbI3)0.85(MAPbBr3)0.15 Perovskites
title_full_unstemmed CH3NH3Cl Assisted Solvent Engineering for Highly Crystallized and Large Grain Size Mixed-Composition (FAPbI3)0.85(MAPbBr3)0.15 Perovskites
title_sort ch3nh3cl assisted solvent engineering for highly crystallized and large grain size mixed-composition (fapbi3)0.85(mapbbr3)0.15 perovskites
publisher MDPI AG
series Crystals
issn 2073-4352
publishDate 2017-09-01
description High-quality mixed-cation lead mixed-halide (FAPbI3)0.85(MAPbBr3)0.15 perovskite films have been prepared using CH3NH3Cl additives via the solvent engineering method. The UV/Vis result shows that the addition of additives leads to enhanced absorptions. XRD and SEM characterizations suggest that compact, pinhole-free and uniform films can be obtained. This is attributable to the crystallization improvement caused by the CH3NH3Cl additives. The power conversion efficiency (PCE) of the F-doped SnO2 (FTO)/compact-TiO2/perovskite/Spiro-OMeTAD/Ag device increases from 15.3% to 16.8% with the help of CH3NH3Cl additive.
topic perovskite
mixed-cation
mixed-halide
additive
CH3NH3Cl
solvent engineering
url https://www.mdpi.com/2073-4352/7/9/272
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AT taiyangzhang ch3nh3classistedsolventengineeringforhighlycrystallizedandlargegrainsizemixedcompositionfapbi3085mapbbr3015perovskites
AT fengxu ch3nh3classistedsolventengineeringforhighlycrystallizedandlargegrainsizemixedcompositionfapbi3085mapbbr3015perovskites
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AT geli ch3nh3classistedsolventengineeringforhighlycrystallizedandlargegrainsizemixedcompositionfapbi3085mapbbr3015perovskites
AT yangyang ch3nh3classistedsolventengineeringforhighlycrystallizedandlargegrainsizemixedcompositionfapbi3085mapbbr3015perovskites
AT yixinzhao ch3nh3classistedsolventengineeringforhighlycrystallizedandlargegrainsizemixedcompositionfapbi3085mapbbr3015perovskites
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