High-Performance Polymer Dispersed Liquid Crystal Enabled by Uniquely Designed Acrylate Monomer
The widespread electro–optical applications of polymer dispersed liquid crystals (PDLCs) are hampered by their high-driving voltage. Attempts to fabricate PDLC devices with low driving voltage sacrifice other desirable features of PDLCs. There is thus a clear need to develop a method to reduce the d...
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doaj-01eea1f9ab98437a9f39574b9a0a53882020-11-25T03:44:44ZengMDPI AGPolymers2073-43602020-07-01121625162510.3390/polym12081625High-Performance Polymer Dispersed Liquid Crystal Enabled by Uniquely Designed Acrylate MonomerRijeesh Kizhakidathazhath0Hiroya Nishikawa1Yasushi Okumura2Hiroki Higuchi3Hirotsugu Kikuchi4Institute for Materials Chemistry and Engineering, Kyushu University, Fukuoka 819-0395, JapanInstitute for Materials Chemistry and Engineering, Kyushu University, Fukuoka 819-0395, JapanInstitute for Materials Chemistry and Engineering, Kyushu University, Fukuoka 819-0395, JapanInstitute for Materials Chemistry and Engineering, Kyushu University, Fukuoka 819-0395, JapanInstitute for Materials Chemistry and Engineering, Kyushu University, Fukuoka 819-0395, JapanThe widespread electro–optical applications of polymer dispersed liquid crystals (PDLCs) are hampered by their high-driving voltage. Attempts to fabricate PDLC devices with low driving voltage sacrifice other desirable features of PDLCs. There is thus a clear need to develop a method to reduce the driving voltage without diminishing other revolutionary features of PDLCs. Herein, we report a low-voltage driven PDLC system achieved through an elegantly simple and uniquely designed acrylate monomer (A3DA) featuring a benzene moiety with a dodecyl terminal chain. The PDLC films were fabricated by the photopolymerization of mono- and di-functional acrylate monomers (19.2 wt%) mixed in a nematic liquid crystal E7 (80 wt%). The PDLC film with A3DA exhibited an abrupt decline of driving voltage by 75% (0.55 V/μm) with a high contrast ratio (16.82) while maintaining other electro–optical properties almost the same as the reference cell. The response time was adjusted to satisfactory by tuning the monomer concentration while maintaining the voltage significantly low (3 ms for a voltage of 0.98 V/μm). Confocal laser scanning microscopy confirmed the polyhedral foam texture morphology with an average mesh size of approximately 2.6 μm, which is less in comparison with the mesh size of reference PDLC (3.4 μm), yet the A3DA-PDLC showed low switching voltage. Thus, the promoted electro–optical properties are believed to be originated from the unique polymer networks formed by A3DA and its weak anchoring behavior on LCs. The present system with such a huge reduction in driving voltage and enhanced electro–optical performance opens up an excellent way for abundant perspective applications of PDLCs.https://www.mdpi.com/2073-4360/12/8/1625liquid crystalsmonomerspolymerizationelectro–optical properties |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Rijeesh Kizhakidathazhath Hiroya Nishikawa Yasushi Okumura Hiroki Higuchi Hirotsugu Kikuchi |
spellingShingle |
Rijeesh Kizhakidathazhath Hiroya Nishikawa Yasushi Okumura Hiroki Higuchi Hirotsugu Kikuchi High-Performance Polymer Dispersed Liquid Crystal Enabled by Uniquely Designed Acrylate Monomer Polymers liquid crystals monomers polymerization electro–optical properties |
author_facet |
Rijeesh Kizhakidathazhath Hiroya Nishikawa Yasushi Okumura Hiroki Higuchi Hirotsugu Kikuchi |
author_sort |
Rijeesh Kizhakidathazhath |
title |
High-Performance Polymer Dispersed Liquid Crystal Enabled by Uniquely Designed Acrylate Monomer |
title_short |
High-Performance Polymer Dispersed Liquid Crystal Enabled by Uniquely Designed Acrylate Monomer |
title_full |
High-Performance Polymer Dispersed Liquid Crystal Enabled by Uniquely Designed Acrylate Monomer |
title_fullStr |
High-Performance Polymer Dispersed Liquid Crystal Enabled by Uniquely Designed Acrylate Monomer |
title_full_unstemmed |
High-Performance Polymer Dispersed Liquid Crystal Enabled by Uniquely Designed Acrylate Monomer |
title_sort |
high-performance polymer dispersed liquid crystal enabled by uniquely designed acrylate monomer |
publisher |
MDPI AG |
series |
Polymers |
issn |
2073-4360 |
publishDate |
2020-07-01 |
description |
The widespread electro–optical applications of polymer dispersed liquid crystals (PDLCs) are hampered by their high-driving voltage. Attempts to fabricate PDLC devices with low driving voltage sacrifice other desirable features of PDLCs. There is thus a clear need to develop a method to reduce the driving voltage without diminishing other revolutionary features of PDLCs. Herein, we report a low-voltage driven PDLC system achieved through an elegantly simple and uniquely designed acrylate monomer (A3DA) featuring a benzene moiety with a dodecyl terminal chain. The PDLC films were fabricated by the photopolymerization of mono- and di-functional acrylate monomers (19.2 wt%) mixed in a nematic liquid crystal E7 (80 wt%). The PDLC film with A3DA exhibited an abrupt decline of driving voltage by 75% (0.55 V/μm) with a high contrast ratio (16.82) while maintaining other electro–optical properties almost the same as the reference cell. The response time was adjusted to satisfactory by tuning the monomer concentration while maintaining the voltage significantly low (3 ms for a voltage of 0.98 V/μm). Confocal laser scanning microscopy confirmed the polyhedral foam texture morphology with an average mesh size of approximately 2.6 μm, which is less in comparison with the mesh size of reference PDLC (3.4 μm), yet the A3DA-PDLC showed low switching voltage. Thus, the promoted electro–optical properties are believed to be originated from the unique polymer networks formed by A3DA and its weak anchoring behavior on LCs. The present system with such a huge reduction in driving voltage and enhanced electro–optical performance opens up an excellent way for abundant perspective applications of PDLCs. |
topic |
liquid crystals monomers polymerization electro–optical properties |
url |
https://www.mdpi.com/2073-4360/12/8/1625 |
work_keys_str_mv |
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