1-Benzyl-3-[3-(naphthalen-2-yloxy)propyl]imidazolium hexafluorophosphate
In the title salt, C23H23N2O+·PF6−, the PF6− anion is highly disordered (occupancy ratios of 0.35:0.35:0.3, 0.7:0.15:0.15, 0.7:0.3 and 0.35:0.35:0.15:0.15) with the four F atoms in the equatorial plane rotating about the axial F—P—...
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International Union of Crystallography
2011-08-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811026663 |
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doaj-01ff2ce97fe24c03a8d0dda944a9ae9c2020-11-25T00:53:19ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-08-01678o2062o206210.1107/S16005368110266631-Benzyl-3-[3-(naphthalen-2-yloxy)propyl]imidazolium hexafluorophosphateKun HuangBin-Xin DuChang-Lu LiuIn the title salt, C23H23N2O+·PF6−, the PF6− anion is highly disordered (occupancy ratios of 0.35:0.35:0.3, 0.7:0.15:0.15, 0.7:0.3 and 0.35:0.35:0.15:0.15) with the four F atoms in the equatorial plane rotating about the axial F—P—F bond. The mean plane of the imidazole ring makes dihedral angles of 82.44 (17) and 14.39 (16)°, respectively, with the mean planes of the benzene ring and the naphthalene ring system. The crystal structure is stabilized by C—H...F hydrogen bonds. In addition, π–π [centroid–centroid distances = 3.7271 (19)–3.8895 (17) Å] and C—H...π interactions are observed.http://scripts.iucr.org/cgi-bin/paper?S1600536811026663 |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Kun Huang Bin-Xin Du Chang-Lu Liu |
| spellingShingle |
Kun Huang Bin-Xin Du Chang-Lu Liu 1-Benzyl-3-[3-(naphthalen-2-yloxy)propyl]imidazolium hexafluorophosphate Acta Crystallographica Section E |
| author_facet |
Kun Huang Bin-Xin Du Chang-Lu Liu |
| author_sort |
Kun Huang |
| title |
1-Benzyl-3-[3-(naphthalen-2-yloxy)propyl]imidazolium hexafluorophosphate |
| title_short |
1-Benzyl-3-[3-(naphthalen-2-yloxy)propyl]imidazolium hexafluorophosphate |
| title_full |
1-Benzyl-3-[3-(naphthalen-2-yloxy)propyl]imidazolium hexafluorophosphate |
| title_fullStr |
1-Benzyl-3-[3-(naphthalen-2-yloxy)propyl]imidazolium hexafluorophosphate |
| title_full_unstemmed |
1-Benzyl-3-[3-(naphthalen-2-yloxy)propyl]imidazolium hexafluorophosphate |
| title_sort |
1-benzyl-3-[3-(naphthalen-2-yloxy)propyl]imidazolium hexafluorophosphate |
| publisher |
International Union of Crystallography |
| series |
Acta Crystallographica Section E |
| issn |
1600-5368 |
| publishDate |
2011-08-01 |
| description |
In the title salt, C23H23N2O+·PF6−, the PF6− anion is highly disordered (occupancy ratios of 0.35:0.35:0.3, 0.7:0.15:0.15, 0.7:0.3 and 0.35:0.35:0.15:0.15) with the four F atoms in the equatorial plane rotating about the axial F—P—F bond. The mean plane of the imidazole ring makes dihedral angles of 82.44 (17) and 14.39 (16)°, respectively, with the mean planes of the benzene ring and the naphthalene ring system. The crystal structure is stabilized by C—H...F hydrogen bonds. In addition, π–π [centroid–centroid distances = 3.7271 (19)–3.8895 (17) Å] and C—H...π interactions are observed. |
| url |
http://scripts.iucr.org/cgi-bin/paper?S1600536811026663 |
| work_keys_str_mv |
AT kunhuang 1benzyl33naphthalen2yloxypropylimidazoliumhexafluorophosphate AT binxindu 1benzyl33naphthalen2yloxypropylimidazoliumhexafluorophosphate AT changluliu 1benzyl33naphthalen2yloxypropylimidazoliumhexafluorophosphate |
| _version_ |
1725238075559247872 |