Crystal structure and Hirshfeld surface analysis of a zinc xanthate complex containing the 2,2′-bipyridine ligand
In the title compound, (2,2′-bipyridine-κ2N,N′)bis(2-methoxyethyl xanthato-κS)zinc(II), [Zn(C4H7O2S2)2(C10H8N2)], the ZnII ion is coordinated to two N atoms of the 2,2′-bipyridine ligand and two S atoms from two 2-methoxyethyl xanthate ligands. The ZnII ion lies on a crystallographic twofold rotatio...
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doaj-02867cf7a6674b25b850dca79159c61a2020-11-25T00:11:17ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902019-12-0175121857186010.1107/S2056989019014968lh5934Crystal structure and Hirshfeld surface analysis of a zinc xanthate complex containing the 2,2′-bipyridine ligandAdnan M. Qadir0Sevgi Kansiz1Georgina M. Rosair2Necmi Dege3Inna S. Safyanova4Department of Chemistry, College of Science, Salahaddin University, Erbil, IraqDepartment of Physics, Faculty of Arts and Sciences, Ondokuz Mayıs University, 55139, Kurupelit, Samsun, TurkeyInstitute of Chemical Sciences, School of Engineering & Physical Sciences, Heriot-Watt University, Edinburgh, EH14 4AS, UKDepartment of Physics, Faculty of Arts and Sciences, Ondokuz Mayıs University, 55139, Kurupelit, Samsun, TurkeyDepartment of Chemistry, Taras Shevchenko National University of Kyiv, 64, Vladimirska Str., Kiev 01601, UkraineIn the title compound, (2,2′-bipyridine-κ2N,N′)bis(2-methoxyethyl xanthato-κS)zinc(II), [Zn(C4H7O2S2)2(C10H8N2)], the ZnII ion is coordinated to two N atoms of the 2,2′-bipyridine ligand and two S atoms from two 2-methoxyethyl xanthate ligands. The ZnII ion lies on a crystallographic twofold rotation axis and has distorted tetrahedral coordination geometry. In the crystal, molecules are linked by weak C—H...O hydrogen bonds, forming supramolecular chains propagating along the a-axis direction. Weak intramolecular C—H...S hydrogen bonds are also observed. The intermolecular contacts in the crystal were further analysed using Hirshfield surface analysis, which indicates that the most significant contacts are H...H (36.3%), followed by S...H/H...S (24.7%), C...H/H...C (15.1%), O...H/H...O (14.4%), N...H/H...N (4.1%) and C...C (2.9%).http://scripts.iucr.org/cgi-bin/paper?S2056989019014968crystal structurexanthatezinc(ii)2,2′-bipyridinehirshfeld surface |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Adnan M. Qadir Sevgi Kansiz Georgina M. Rosair Necmi Dege Inna S. Safyanova |
spellingShingle |
Adnan M. Qadir Sevgi Kansiz Georgina M. Rosair Necmi Dege Inna S. Safyanova Crystal structure and Hirshfeld surface analysis of a zinc xanthate complex containing the 2,2′-bipyridine ligand Acta Crystallographica Section E: Crystallographic Communications crystal structure xanthate zinc(ii) 2,2′-bipyridine hirshfeld surface |
author_facet |
Adnan M. Qadir Sevgi Kansiz Georgina M. Rosair Necmi Dege Inna S. Safyanova |
author_sort |
Adnan M. Qadir |
title |
Crystal structure and Hirshfeld surface analysis of a zinc xanthate complex containing the 2,2′-bipyridine ligand |
title_short |
Crystal structure and Hirshfeld surface analysis of a zinc xanthate complex containing the 2,2′-bipyridine ligand |
title_full |
Crystal structure and Hirshfeld surface analysis of a zinc xanthate complex containing the 2,2′-bipyridine ligand |
title_fullStr |
Crystal structure and Hirshfeld surface analysis of a zinc xanthate complex containing the 2,2′-bipyridine ligand |
title_full_unstemmed |
Crystal structure and Hirshfeld surface analysis of a zinc xanthate complex containing the 2,2′-bipyridine ligand |
title_sort |
crystal structure and hirshfeld surface analysis of a zinc xanthate complex containing the 2,2′-bipyridine ligand |
publisher |
International Union of Crystallography |
series |
Acta Crystallographica Section E: Crystallographic Communications |
issn |
2056-9890 |
publishDate |
2019-12-01 |
description |
In the title compound, (2,2′-bipyridine-κ2N,N′)bis(2-methoxyethyl xanthato-κS)zinc(II), [Zn(C4H7O2S2)2(C10H8N2)], the ZnII ion is coordinated to two N atoms of the 2,2′-bipyridine ligand and two S atoms from two 2-methoxyethyl xanthate ligands. The ZnII ion lies on a crystallographic twofold rotation axis and has distorted tetrahedral coordination geometry. In the crystal, molecules are linked by weak C—H...O hydrogen bonds, forming supramolecular chains propagating along the a-axis direction. Weak intramolecular C—H...S hydrogen bonds are also observed. The intermolecular contacts in the crystal were further analysed using Hirshfield surface analysis, which indicates that the most significant contacts are H...H (36.3%), followed by S...H/H...S (24.7%), C...H/H...C (15.1%), O...H/H...O (14.4%), N...H/H...N (4.1%) and C...C (2.9%). |
topic |
crystal structure xanthate zinc(ii) 2,2′-bipyridine hirshfeld surface |
url |
http://scripts.iucr.org/cgi-bin/paper?S2056989019014968 |
work_keys_str_mv |
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