Synthesis, Mesomorphism and the Optical Properties of Alkyl-deuterated Nematogenic 4-[(2,6-Difluorophenyl)ethynyl]biphenyls

• Main Authors: Jakub Herman, Piotr Harmata, Michał Czerwiński, Olga Strzeżysz, Marta Pytlarczyk, Monika Zając, Przemysław Kula
• Format: Article
• Language: English
• Published: MDPI AG 2021-08-01
• Series: Materials
• Subjects: infrared; flow chemistry; deuterium addition; nematic
• Online Access: https://www.mdpi.com/1996-1944/14/16/4653

The synthesis and characterization of new deuterated liquid crystal (LC) compounds based on phenyl tolane core is described in this paper. The work presents an alternative molecular approach to the conventional LC design. Correlations between molecular structure and mesomorphic and optical properties for compounds which are alkyl-hydrogen terminated and alkyl-deuterium, have been drawn. The compounds are characterized by mass spectrometry (electron ionization) analysis and infrared spectroscopy. They show enantiotropic nematic behavior in a broad temperature range, confirmed by a polarizing thermomicroscopy and differential scanning calorimetry. Detailed synthetic procedures are attached. Synthesized compounds show a significantly reduced absorption in the near-infrared (NIR) and medium-wavelength infrared (MWIR) radiation range, and stand as promising components of medium to highly birefringent liquid crystalline mixtures.