The Chemistry of DPPH<sup>·</sup> Free Radical and Congeners
Since the discovery in 1922 of 2,2-diphenyl-1-(2,4,6-trinitrophenyl) hydrazyl stable free radical (DPPH<sup>·</sup>), the chemistry of such open-shell compounds has developed continuously, allowing for both theoretical and practical advances in the free radical chemistry area. This revie...
Main Author: | |
---|---|
Format: | Article |
Language: | English |
Published: |
MDPI AG
2021-02-01
|
Series: | International Journal of Molecular Sciences |
Subjects: | |
Online Access: | https://www.mdpi.com/1422-0067/22/4/1545 |
id |
doaj-0304819ded1c4f3f8f0b9b1d06fc5ddd |
---|---|
record_format |
Article |
spelling |
doaj-0304819ded1c4f3f8f0b9b1d06fc5ddd2021-02-04T00:06:25ZengMDPI AGInternational Journal of Molecular Sciences1661-65961422-00672021-02-01221545154510.3390/ijms22041545The Chemistry of DPPH<sup>·</sup> Free Radical and CongenersPetre Ionita0Faculty of Chemistry, University of Bucharest, 050663 Bucharest, RomaniaSince the discovery in 1922 of 2,2-diphenyl-1-(2,4,6-trinitrophenyl) hydrazyl stable free radical (DPPH<sup>·</sup>), the chemistry of such open-shell compounds has developed continuously, allowing for both theoretical and practical advances in the free radical chemistry area. This review presents the important, general and modern aspects of the chemistry of hydrazyl free radicals and the science behind it.https://www.mdpi.com/1422-0067/22/4/1545hydrazylfree radicalorganic synthesisspinredoxESR |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Petre Ionita |
spellingShingle |
Petre Ionita The Chemistry of DPPH<sup>·</sup> Free Radical and Congeners International Journal of Molecular Sciences hydrazyl free radical organic synthesis spin redox ESR |
author_facet |
Petre Ionita |
author_sort |
Petre Ionita |
title |
The Chemistry of DPPH<sup>·</sup> Free Radical and Congeners |
title_short |
The Chemistry of DPPH<sup>·</sup> Free Radical and Congeners |
title_full |
The Chemistry of DPPH<sup>·</sup> Free Radical and Congeners |
title_fullStr |
The Chemistry of DPPH<sup>·</sup> Free Radical and Congeners |
title_full_unstemmed |
The Chemistry of DPPH<sup>·</sup> Free Radical and Congeners |
title_sort |
chemistry of dpph<sup>·</sup> free radical and congeners |
publisher |
MDPI AG |
series |
International Journal of Molecular Sciences |
issn |
1661-6596 1422-0067 |
publishDate |
2021-02-01 |
description |
Since the discovery in 1922 of 2,2-diphenyl-1-(2,4,6-trinitrophenyl) hydrazyl stable free radical (DPPH<sup>·</sup>), the chemistry of such open-shell compounds has developed continuously, allowing for both theoretical and practical advances in the free radical chemistry area. This review presents the important, general and modern aspects of the chemistry of hydrazyl free radicals and the science behind it. |
topic |
hydrazyl free radical organic synthesis spin redox ESR |
url |
https://www.mdpi.com/1422-0067/22/4/1545 |
work_keys_str_mv |
AT petreionita thechemistryofdpphsupsupfreeradicalandcongeners AT petreionita chemistryofdpphsupsupfreeradicalandcongeners |
_version_ |
1724285674895441920 |