Synthesis of Highly Effective Novel Graphene Oxide-Polyethylene Glycol-Polyvinyl Alcohol Nanocomposite Hydrogel For Copper Removal

A novel Graphene oxide-polyethylene glycol and polyvinyl alcohol (GO-PEG-PVA) triple network hydrogel were prepared to remove Copper(II) ion from its aqueous solution. The structures, morphologies, and properties of graphene oxide (GO), the composite GO-PEG-PVA and PEG-PVA were characterized using F...

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Bibliographic Details
Main Authors: Eman Serag, Ahmed El Nemr, Azza El-Maghraby
Format: Article
Language:English
Published: Iranian Environmental Mutagen Society 2017-10-01
Series:Journal of Water and Environmental Nanotechnology
Subjects:
Online Access:http://www.jwent.net/article_28430_d0963ae5eae3179383d1bcff1a7a6a61.pdf
Description
Summary:A novel Graphene oxide-polyethylene glycol and polyvinyl alcohol (GO-PEG-PVA) triple network hydrogel were prepared to remove Copper(II) ion from its aqueous solution. The structures, morphologies, and properties of graphene oxide (GO), the composite GO-PEG-PVA and PEG-PVA were characterized using FTIR, X-ray diffraction, Scanning Electronic Microscope and Thermal Gravimetric analysis. A series of systematic batch adsorption experiments were conducted to study the adsorption property of GO, GO-PEG-PVA hydrogel and PEG-PVA hydrogel under different conditions (e.g. pH, contact time and Cu2+ ions concentration). The high adsorption capacity, easy regeneration, and effective adsorption–desorption results proved that the prepared GO-PEG-PVA composite hydrogel could be an effective adsorbent in removing Cu2+ ion from its aqueous solution. The maximum adsorption capacities were found to be 917, 900 and 423 mg g–1 for GO-PEG-PVA hydrogel, GO and PEG-PVA hydrogel, respectively at pH 5, 25 °C and Cu2+ ions’ concentration 500 mg l–1. The removal efficiency of the recycled GO-PEG-PVA hydrogel were 83, 81, 80 and 79% for the first four times, which proved efficient reusability.
ISSN:2476-7204
2476-6615