3-Bromomethyl-4-methoxy-2-(2-nitrophenyl)-9-phenylsulfonyl-9H-carbazole

3-Bromomethyl-4-methoxy-2-(2-nitrophenyl)-9-phenylsulfonyl-9H-carbazole

In the title compound, C26H19BrN2O5S, the carbazole tricycle is essentially planar, with the largest deviation being 0.126 (3) Å for the C atom connected to the nitrophenyl group. The carbazole moiety is almost orthogonal to the benzene rings of the adjacent phenylsulfonyl and nitrophenyl groups, ma...

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Main Authors: S. Gopinath, K. Sethusankar, Velu Saravanan, Arasambattu K. Mohanakrishnan
Format: Article
Language:English
Published: International Union of Crystallography 2014-06-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S160053681401143X
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spelling doaj-0482cee46b594cd3b16a21872da582af2020-11-25T02:46:35ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682014-06-01706o707o70810.1107/S160053681401143Xld21273-Bromomethyl-4-methoxy-2-(2-nitrophenyl)-9-phenylsulfonyl-9H-carbazoleS. Gopinath0K. Sethusankar1Velu Saravanan2Arasambattu K. Mohanakrishnan3Department of Physics, RKM Vivekananda College (Autonomous), Chennai 600 004, IndiaDepartment of Physics, RKM Vivekananda College (Autonomous), Chennai 600 004, IndiaDepartment of Organic Chemistry, University of Madras, Guindy Campus, Chennai 600 025, IndiaDepartment of Organic Chemistry, University of Madras, Guindy Campus, Chennai 600 025, IndiaIn the title compound, C26H19BrN2O5S, the carbazole tricycle is essentially planar, with the largest deviation being 0.126 (3) Å for the C atom connected to the nitrophenyl group. The carbazole moiety is almost orthogonal to the benzene rings of the adjacent phenylsulfonyl and nitrophenyl groups, making dihedral angles of 85.43 (15) and 88.62 (12)°, respectively. The molecular conformation is stabilized by two C—H...O hydrogen bonds involving the sulfone group, which form similar six-membered rings. In the crystal, molecules symmetrically related by a glide plane are linked in C(6) chains parallel to [001] by C—H...O hydrogen bonds formed with the participation of the nitro group. The chains are reinforced by additional C—H...π interactions.http://scripts.iucr.org/cgi-bin/paper?S160053681401143X
collection DOAJ
language English
format Article
sources DOAJ
author S. Gopinath
K. Sethusankar
Velu Saravanan
Arasambattu K. Mohanakrishnan
spellingShingle S. Gopinath
K. Sethusankar
Velu Saravanan
Arasambattu K. Mohanakrishnan
3-Bromomethyl-4-methoxy-2-(2-nitrophenyl)-9-phenylsulfonyl-9H-carbazole
Acta Crystallographica Section E
author_facet S. Gopinath
K. Sethusankar
Velu Saravanan
Arasambattu K. Mohanakrishnan
author_sort S. Gopinath
title 3-Bromomethyl-4-methoxy-2-(2-nitrophenyl)-9-phenylsulfonyl-9H-carbazole
title_short 3-Bromomethyl-4-methoxy-2-(2-nitrophenyl)-9-phenylsulfonyl-9H-carbazole
title_full 3-Bromomethyl-4-methoxy-2-(2-nitrophenyl)-9-phenylsulfonyl-9H-carbazole
title_fullStr 3-Bromomethyl-4-methoxy-2-(2-nitrophenyl)-9-phenylsulfonyl-9H-carbazole
title_full_unstemmed 3-Bromomethyl-4-methoxy-2-(2-nitrophenyl)-9-phenylsulfonyl-9H-carbazole
title_sort 3-bromomethyl-4-methoxy-2-(2-nitrophenyl)-9-phenylsulfonyl-9h-carbazole
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2014-06-01
description In the title compound, C26H19BrN2O5S, the carbazole tricycle is essentially planar, with the largest deviation being 0.126 (3) Å for the C atom connected to the nitrophenyl group. The carbazole moiety is almost orthogonal to the benzene rings of the adjacent phenylsulfonyl and nitrophenyl groups, making dihedral angles of 85.43 (15) and 88.62 (12)°, respectively. The molecular conformation is stabilized by two C—H...O hydrogen bonds involving the sulfone group, which form similar six-membered rings. In the crystal, molecules symmetrically related by a glide plane are linked in C(6) chains parallel to [001] by C—H...O hydrogen bonds formed with the participation of the nitro group. The chains are reinforced by additional C—H...π interactions.
url http://scripts.iucr.org/cgi-bin/paper?S160053681401143X
work_keys_str_mv AT sgopinath 3bromomethyl4methoxy22nitrophenyl9phenylsulfonyl9hcarbazole
AT ksethusankar 3bromomethyl4methoxy22nitrophenyl9phenylsulfonyl9hcarbazole
AT velusaravanan 3bromomethyl4methoxy22nitrophenyl9phenylsulfonyl9hcarbazole
AT arasambattukmohanakrishnan 3bromomethyl4methoxy22nitrophenyl9phenylsulfonyl9hcarbazole
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