(Benzyl isocyanide-κC1)chlorido(2-chloro-3-dimethylamino-1-phenylprop-1-en-1-yl-κ2C1,N)palladium(II)

(Benzyl isocyanide-κC1)chlorido(2-chloro-3-dimethylamino-1-phenylprop-1-en-1-yl-κ2C1,N)palladium(II)

In the title compound, [Pd(C11H13ClN)Cl(C8H7N)], which crystallized in the chiral space group P212121, the PdII atom is coordinated by two C atoms, a Csp2 atom of the 2-chloro-3-dimethylamino-1-phenylprop-1-en-1-yl ligand and a Csp atom from the benzyl isocyanide ligand, as well as an N atom of the...

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Main Authors: Ana C. Mafud, Milene A. R. Oliviera, Maria T. P. Gambardella
Format: Article
Language:English
Published: International Union of Crystallography 2013-01-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812049768
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spelling doaj-04de04e5b5b846a5bc0192e8f1334dcb2020-11-25T01:05:18ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682013-01-01691m36m3610.1107/S1600536812049768(Benzyl isocyanide-κC1)chlorido(2-chloro-3-dimethylamino-1-phenylprop-1-en-1-yl-κ2C1,N)palladium(II)Ana C. MafudMilene A. R. OlivieraMaria T. P. GambardellaIn the title compound, [Pd(C11H13ClN)Cl(C8H7N)], which crystallized in the chiral space group P212121, the PdII atom is coordinated by two C atoms, a Csp2 atom of the 2-chloro-3-dimethylamino-1-phenylprop-1-en-1-yl ligand and a Csp atom from the benzyl isocyanide ligand, as well as an N atom of the ligand and a Cl atom, in a square-planar geometry. In the complex, there is a short C—H...Cl hydrogen bond and a C—H...π interaction. In the crystal, molecules are linked via C—H...Cl hydrogen bonds, forming chains along the a-axis direction.http://scripts.iucr.org/cgi-bin/paper?S1600536812049768
collection DOAJ
language English
format Article
sources DOAJ
author Ana C. Mafud
Milene A. R. Oliviera
Maria T. P. Gambardella
spellingShingle Ana C. Mafud
Milene A. R. Oliviera
Maria T. P. Gambardella
(Benzyl isocyanide-κC1)chlorido(2-chloro-3-dimethylamino-1-phenylprop-1-en-1-yl-κ2C1,N)palladium(II)
Acta Crystallographica Section E
author_facet Ana C. Mafud
Milene A. R. Oliviera
Maria T. P. Gambardella
author_sort Ana C. Mafud
title (Benzyl isocyanide-κC1)chlorido(2-chloro-3-dimethylamino-1-phenylprop-1-en-1-yl-κ2C1,N)palladium(II)
title_short (Benzyl isocyanide-κC1)chlorido(2-chloro-3-dimethylamino-1-phenylprop-1-en-1-yl-κ2C1,N)palladium(II)
title_full (Benzyl isocyanide-κC1)chlorido(2-chloro-3-dimethylamino-1-phenylprop-1-en-1-yl-κ2C1,N)palladium(II)
title_fullStr (Benzyl isocyanide-κC1)chlorido(2-chloro-3-dimethylamino-1-phenylprop-1-en-1-yl-κ2C1,N)palladium(II)
title_full_unstemmed (Benzyl isocyanide-κC1)chlorido(2-chloro-3-dimethylamino-1-phenylprop-1-en-1-yl-κ2C1,N)palladium(II)
title_sort (benzyl isocyanide-κc1)chlorido(2-chloro-3-dimethylamino-1-phenylprop-1-en-1-yl-κ2c1,n)palladium(ii)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2013-01-01
description In the title compound, [Pd(C11H13ClN)Cl(C8H7N)], which crystallized in the chiral space group P212121, the PdII atom is coordinated by two C atoms, a Csp2 atom of the 2-chloro-3-dimethylamino-1-phenylprop-1-en-1-yl ligand and a Csp atom from the benzyl isocyanide ligand, as well as an N atom of the ligand and a Cl atom, in a square-planar geometry. In the complex, there is a short C—H...Cl hydrogen bond and a C—H...π interaction. In the crystal, molecules are linked via C—H...Cl hydrogen bonds, forming chains along the a-axis direction.
url http://scripts.iucr.org/cgi-bin/paper?S1600536812049768
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AT milenearoliviera benzylisocyanide954c1chlorido2chloro3dimethylamino1phenylprop1en1yl9542c1npalladiumii
AT mariatpgambardella benzylisocyanide954c1chlorido2chloro3dimethylamino1phenylprop1en1yl9542c1npalladiumii
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