Methane Transport during a Controlled Release in the Vadose Zone

• Main Authors: Mark Felice, Nick de Sieyes, Juan Peng, Radomir Schmidt, Maya Buelow, Parisa Jourabchi, Kate Scow, Douglas Mackay
• Format: Article
• Language: English
• Published: Wiley 2018-07-01
• Series: Vadose Zone Journal
• Online Access: https://dl.sciencesocieties.org/publications/vzj/articles/17/1/180028

Shallow, small-rate releases of ethanol-blended fuels from underground storage tanks (USTs) may be quite common and result in subsurface CH generation. However, vadose zone transport of CH generated from these fuel releases is poorly understood, despite the potential to promote vapor intrusion or create explosion hazards. In this study, we simulated shallow CH generation with a controlled subsurface CH release from July 2014 to February 2015 to characterize subsurface CH migration and surface emissions and to determine environmental controls on CH fate and transport. July 2014 through November 2014 was an extended period of drought followed by precipitation during December 2014. Throughout the experiment, under varied CH injection rates, CH formed a radially symmetrical plume around the injection point. Surface efflux during the drought period of the experiment was relatively high and stable, with approximately 10 to 11 and 34 to 52% of injected CH reaching the ground surface during the low- and high-rate injections, respectively. Following the period of precipitation and increased soil moisture, efflux dropped and stabilized at approximately 1% of injected CH, even as soil moisture began to decrease again. Tracer and inhibitor experiments and estimates of soil diffusivity suggest that microbial CH oxidation was responsible for the observed drop in efflux. The decrease in efflux only after soil moisture increased suggests a strong environmental control over the transport and oxidation of vadose zone CH.