μ-4,4′-Bipyridine-κ2N:N′-bis[aqua(4,4′-bipyridine-κN)(l-valinato-κ2N,O)copper(II)] dinitrate dihydrate

μ-4,4′-Bipyridine-κ2N:N′-bis[aqua(4,4′-bipyridine-κN)(l-valinato-κ2N,O)copper(II)] dinitrate dihydrate

In the title dinuclear complex, [Cu2(C5H10NO2)2(C10H8N2)3(H2O)2](NO3)2·2H2O, each of the two l-valinate anions chelates a CuII center through the amino N and carboxylate O atom, forming a five-membered ring. A 4,4′-bipyridine molecule bridges two water-coordinated Cu atoms, each o...

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Main Authors: Mao-Chun Hong, Ben-Yong Lou
Format: Article
Language:English
Published: International Union of Crystallography 2008-02-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536808002109
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spelling doaj-05979e764932468a90337d75a87dbdba2020-11-25T02:14:00ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-02-01642m405m40510.1107/S1600536808002109μ-4,4′-Bipyridine-κ2N:N′-bis[aqua(4,4′-bipyridine-κN)(l-valinato-κ2N,O)copper(II)] dinitrate dihydrateMao-Chun HongBen-Yong LouIn the title dinuclear complex, [Cu2(C5H10NO2)2(C10H8N2)3(H2O)2](NO3)2·2H2O, each of the two l-valinate anions chelates a CuII center through the amino N and carboxylate O atom, forming a five-membered ring. A 4,4′-bipyridine molecule bridges two water-coordinated Cu atoms, each of which is connected to another 4,4′-bipyridine, giving rise to a square-pyramidal coordination geometry for the CuII centers. The dinuclear dications, nitrate anions and uncoordinated water molecules are linked into a two-dimensional structure.http://scripts.iucr.org/cgi-bin/paper?S1600536808002109
collection DOAJ
language English
format Article
sources DOAJ
author Mao-Chun Hong
Ben-Yong Lou
spellingShingle Mao-Chun Hong
Ben-Yong Lou
μ-4,4′-Bipyridine-κ2N:N′-bis[aqua(4,4′-bipyridine-κN)(l-valinato-κ2N,O)copper(II)] dinitrate dihydrate
Acta Crystallographica Section E
author_facet Mao-Chun Hong
Ben-Yong Lou
author_sort Mao-Chun Hong
title μ-4,4′-Bipyridine-κ2N:N′-bis[aqua(4,4′-bipyridine-κN)(l-valinato-κ2N,O)copper(II)] dinitrate dihydrate
title_short μ-4,4′-Bipyridine-κ2N:N′-bis[aqua(4,4′-bipyridine-κN)(l-valinato-κ2N,O)copper(II)] dinitrate dihydrate
title_full μ-4,4′-Bipyridine-κ2N:N′-bis[aqua(4,4′-bipyridine-κN)(l-valinato-κ2N,O)copper(II)] dinitrate dihydrate
title_fullStr μ-4,4′-Bipyridine-κ2N:N′-bis[aqua(4,4′-bipyridine-κN)(l-valinato-κ2N,O)copper(II)] dinitrate dihydrate
title_full_unstemmed μ-4,4′-Bipyridine-κ2N:N′-bis[aqua(4,4′-bipyridine-κN)(l-valinato-κ2N,O)copper(II)] dinitrate dihydrate
title_sort μ-4,4′-bipyridine-κ2n:n′-bis[aqua(4,4′-bipyridine-κn)(l-valinato-κ2n,o)copper(ii)] dinitrate dihydrate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2008-02-01
description In the title dinuclear complex, [Cu2(C5H10NO2)2(C10H8N2)3(H2O)2](NO3)2·2H2O, each of the two l-valinate anions chelates a CuII center through the amino N and carboxylate O atom, forming a five-membered ring. A 4,4′-bipyridine molecule bridges two water-coordinated Cu atoms, each of which is connected to another 4,4′-bipyridine, giving rise to a square-pyramidal coordination geometry for the CuII centers. The dinuclear dications, nitrate anions and uncoordinated water molecules are linked into a two-dimensional structure.
url http://scripts.iucr.org/cgi-bin/paper?S1600536808002109
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AT benyonglou 956448242bipyridine9542nn8242bisaqua448242bipyridine954nlvalinato9542nocopperiidinitratedihydrate
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