A rigid and healable polymer cross-linked by weak but abundant Zn(II)-carboxylate interactions

Combining solid-like properties with fast self-healing is a great challenge due to slow diffusion dynamics. Here the authors demonstrate a rigid and healable material by using weak but abundant coordination bonds to crosslink a PDMS polymer.

Bibliographic Details
Main Authors:	Jian-Cheng Lai, Lan Li, Da-Peng Wang, Min-Hao Zhang, Sheng-Ran Mo, Xue Wang, Ke-Yu Zeng, Cheng-Hui Li, Qing Jiang, Xiao-Zeng You, Jing-Lin Zuo
Format:	Article
Language:	English
Published:	Nature Publishing Group 2018-07-01
Series:	Nature Communications
Online Access:	https://doi.org/10.1038/s41467-018-05285-3

id	doaj-05b7eb61d2e5414dafcd9c97d87e45e5
record_format	Article
spelling	doaj-05b7eb61d2e5414dafcd9c97d87e45e52021-05-11T09:55:33ZengNature Publishing GroupNature Communications2041-17232018-07-01911910.1038/s41467-018-05285-3A rigid and healable polymer cross-linked by weak but abundant Zn(II)-carboxylate interactionsJian-Cheng Lai0Lan Li1Da-Peng Wang2Min-Hao Zhang3Sheng-Ran Mo4Xue Wang5Ke-Yu Zeng6Cheng-Hui Li7Qing Jiang8Xiao-Zeng You9Jing-Lin Zuo10State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing National Laboratory of Microstructures, Collaborative Innovation Center of Advanced Microstructures, Nanjing UniversityDepartment of Sports Medicine and Adult Reconstructive Surgery, Drum Tower Hospital affiliated to Medical School of Nanjing UniversityState Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing National Laboratory of Microstructures, Collaborative Innovation Center of Advanced Microstructures, Nanjing UniversityState Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing National Laboratory of Microstructures, Collaborative Innovation Center of Advanced Microstructures, Nanjing UniversityState Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing National Laboratory of Microstructures, Collaborative Innovation Center of Advanced Microstructures, Nanjing UniversityState Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing National Laboratory of Microstructures, Collaborative Innovation Center of Advanced Microstructures, Nanjing UniversityState Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing National Laboratory of Microstructures, Collaborative Innovation Center of Advanced Microstructures, Nanjing UniversityState Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing National Laboratory of Microstructures, Collaborative Innovation Center of Advanced Microstructures, Nanjing UniversityDepartment of Sports Medicine and Adult Reconstructive Surgery, Drum Tower Hospital affiliated to Medical School of Nanjing UniversityState Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing National Laboratory of Microstructures, Collaborative Innovation Center of Advanced Microstructures, Nanjing UniversityState Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing National Laboratory of Microstructures, Collaborative Innovation Center of Advanced Microstructures, Nanjing UniversityCombining solid-like properties with fast self-healing is a great challenge due to slow diffusion dynamics. Here the authors demonstrate a rigid and healable material by using weak but abundant coordination bonds to crosslink a PDMS polymer.https://doi.org/10.1038/s41467-018-05285-3
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	Jian-Cheng Lai Lan Li Da-Peng Wang Min-Hao Zhang Sheng-Ran Mo Xue Wang Ke-Yu Zeng Cheng-Hui Li Qing Jiang Xiao-Zeng You Jing-Lin Zuo
spellingShingle	Jian-Cheng Lai Lan Li Da-Peng Wang Min-Hao Zhang Sheng-Ran Mo Xue Wang Ke-Yu Zeng Cheng-Hui Li Qing Jiang Xiao-Zeng You Jing-Lin Zuo A rigid and healable polymer cross-linked by weak but abundant Zn(II)-carboxylate interactions Nature Communications
author_facet	Jian-Cheng Lai Lan Li Da-Peng Wang Min-Hao Zhang Sheng-Ran Mo Xue Wang Ke-Yu Zeng Cheng-Hui Li Qing Jiang Xiao-Zeng You Jing-Lin Zuo
author_sort	Jian-Cheng Lai
title	A rigid and healable polymer cross-linked by weak but abundant Zn(II)-carboxylate interactions
title_short	A rigid and healable polymer cross-linked by weak but abundant Zn(II)-carboxylate interactions
title_full	A rigid and healable polymer cross-linked by weak but abundant Zn(II)-carboxylate interactions
title_fullStr	A rigid and healable polymer cross-linked by weak but abundant Zn(II)-carboxylate interactions
title_full_unstemmed	A rigid and healable polymer cross-linked by weak but abundant Zn(II)-carboxylate interactions
title_sort	rigid and healable polymer cross-linked by weak but abundant zn(ii)-carboxylate interactions
publisher	Nature Publishing Group
series	Nature Communications
issn	2041-1723
publishDate	2018-07-01
description	Combining solid-like properties with fast self-healing is a great challenge due to slow diffusion dynamics. Here the authors demonstrate a rigid and healable material by using weak but abundant coordination bonds to crosslink a PDMS polymer.
url	https://doi.org/10.1038/s41467-018-05285-3
work_keys_str_mv	AT jianchenglai arigidandhealablepolymercrosslinkedbyweakbutabundantzniicarboxylateinteractions AT lanli arigidandhealablepolymercrosslinkedbyweakbutabundantzniicarboxylateinteractions AT dapengwang arigidandhealablepolymercrosslinkedbyweakbutabundantzniicarboxylateinteractions AT minhaozhang arigidandhealablepolymercrosslinkedbyweakbutabundantzniicarboxylateinteractions AT shengranmo arigidandhealablepolymercrosslinkedbyweakbutabundantzniicarboxylateinteractions AT xuewang arigidandhealablepolymercrosslinkedbyweakbutabundantzniicarboxylateinteractions AT keyuzeng arigidandhealablepolymercrosslinkedbyweakbutabundantzniicarboxylateinteractions AT chenghuili arigidandhealablepolymercrosslinkedbyweakbutabundantzniicarboxylateinteractions AT qingjiang arigidandhealablepolymercrosslinkedbyweakbutabundantzniicarboxylateinteractions AT xiaozengyou arigidandhealablepolymercrosslinkedbyweakbutabundantzniicarboxylateinteractions AT jinglinzuo arigidandhealablepolymercrosslinkedbyweakbutabundantzniicarboxylateinteractions AT jianchenglai rigidandhealablepolymercrosslinkedbyweakbutabundantzniicarboxylateinteractions AT lanli rigidandhealablepolymercrosslinkedbyweakbutabundantzniicarboxylateinteractions AT dapengwang rigidandhealablepolymercrosslinkedbyweakbutabundantzniicarboxylateinteractions AT minhaozhang rigidandhealablepolymercrosslinkedbyweakbutabundantzniicarboxylateinteractions AT shengranmo rigidandhealablepolymercrosslinkedbyweakbutabundantzniicarboxylateinteractions AT xuewang rigidandhealablepolymercrosslinkedbyweakbutabundantzniicarboxylateinteractions AT keyuzeng rigidandhealablepolymercrosslinkedbyweakbutabundantzniicarboxylateinteractions AT chenghuili rigidandhealablepolymercrosslinkedbyweakbutabundantzniicarboxylateinteractions AT qingjiang rigidandhealablepolymercrosslinkedbyweakbutabundantzniicarboxylateinteractions AT xiaozengyou rigidandhealablepolymercrosslinkedbyweakbutabundantzniicarboxylateinteractions AT jinglinzuo rigidandhealablepolymercrosslinkedbyweakbutabundantzniicarboxylateinteractions
_version_	1721448903040040960

A rigid and healable polymer cross-linked by weak but abundant Zn(II)-carboxylate interactions

Similar Items