(E)-Methyl N′-[(1H-indol-3-yl)methylidene]hydrazinecarboxylate 0.25-hydrate

(E)-Methyl N′-[(1H-indol-3-yl)methylidene]hydrazinecarboxylate 0.25-hydrate

The asymmetric unit of the title compound, C11H11N3O2·0.25H2O, contains two independent organic molecules and a water molecule, which lies on a twofold rotation axis. The side chains of the two molecules have slightly different orientations, the C=N—N—C torsi...

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Main Authors: Lu-Ping Lv, Tie-Ming Yu, Wen-Bo Yu, Xian-Chao Hu
Format: Article
Language:English
Published: International Union of Crystallography 2011-08-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811026249
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spelling doaj-06708907690e47a481f04483abdffad82020-11-25T00:50:38ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-08-01678o1956o195610.1107/S1600536811026249(E)-Methyl N′-[(1H-indol-3-yl)methylidene]hydrazinecarboxylate 0.25-hydrateLu-Ping LvTie-Ming YuWen-Bo YuXian-Chao HuThe asymmetric unit of the title compound, C11H11N3O2·0.25H2O, contains two independent organic molecules and a water molecule, which lies on a twofold rotation axis. The side chains of the two molecules have slightly different orientations, the C=N—N—C torsion angle being −163.03 (15)° in one and −177.52 (14)° in the other, with each adopting a trans configuration with respect to the C=N bond. In the crystal, molecules are linked into chains extending along b by N—H...O, O—H...N and O—H...O hydrogen bonds and in addition, four intermolecular C—H...π interactions are present.http://scripts.iucr.org/cgi-bin/paper?S1600536811026249
collection DOAJ
language English
format Article
sources DOAJ
author Lu-Ping Lv
Tie-Ming Yu
Wen-Bo Yu
Xian-Chao Hu
spellingShingle Lu-Ping Lv
Tie-Ming Yu
Wen-Bo Yu
Xian-Chao Hu
(E)-Methyl N′-[(1H-indol-3-yl)methylidene]hydrazinecarboxylate 0.25-hydrate
Acta Crystallographica Section E
author_facet Lu-Ping Lv
Tie-Ming Yu
Wen-Bo Yu
Xian-Chao Hu
author_sort Lu-Ping Lv
title (E)-Methyl N′-[(1H-indol-3-yl)methylidene]hydrazinecarboxylate 0.25-hydrate
title_short (E)-Methyl N′-[(1H-indol-3-yl)methylidene]hydrazinecarboxylate 0.25-hydrate
title_full (E)-Methyl N′-[(1H-indol-3-yl)methylidene]hydrazinecarboxylate 0.25-hydrate
title_fullStr (E)-Methyl N′-[(1H-indol-3-yl)methylidene]hydrazinecarboxylate 0.25-hydrate
title_full_unstemmed (E)-Methyl N′-[(1H-indol-3-yl)methylidene]hydrazinecarboxylate 0.25-hydrate
title_sort (e)-methyl n′-[(1h-indol-3-yl)methylidene]hydrazinecarboxylate 0.25-hydrate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2011-08-01
description The asymmetric unit of the title compound, C11H11N3O2·0.25H2O, contains two independent organic molecules and a water molecule, which lies on a twofold rotation axis. The side chains of the two molecules have slightly different orientations, the C=N—N—C torsion angle being −163.03 (15)° in one and −177.52 (14)° in the other, with each adopting a trans configuration with respect to the C=N bond. In the crystal, molecules are linked into chains extending along b by N—H...O, O—H...N and O—H...O hydrogen bonds and in addition, four intermolecular C—H...π interactions are present.
url http://scripts.iucr.org/cgi-bin/paper?S1600536811026249
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AT tiemingyu emethylnamp82421hindol3ylmethylidenehydrazinecarboxylate025hydrate
AT wenboyu emethylnamp82421hindol3ylmethylidenehydrazinecarboxylate025hydrate
AT xianchaohu emethylnamp82421hindol3ylmethylidenehydrazinecarboxylate025hydrate
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