Photodegradation of Antibiotics by Noncovalent Porphyrin-Functionalized TiO<sub>2</sub> in Water for the Bacterial Antibiotic Resistance Risk Management
Antibiotics represent essential drugs to contrast the insurgence of bacterial infections in humans and animals. Their extensive use in livestock farming, including aquaculture, has improved production performances and food safety. However, their overuse can implicate a risk of water pollution and re...
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doaj-07a26feadf8f4fb783d13b1c51bb19972020-11-25T03:08:25ZengMDPI AGInternational Journal of Molecular Sciences1661-65961422-00672020-05-01213775377510.3390/ijms21113775Photodegradation of Antibiotics by Noncovalent Porphyrin-Functionalized TiO<sub>2</sub> in Water for the Bacterial Antibiotic Resistance Risk ManagementMassimiliano Gaeta0Giuseppe Sanfilippo1Aurore Fraix2Giuseppe Sortino3Matteo Barcellona4Gea Oliveri Conti5Maria Elena Fragalà6Margherita Ferrante7Roberto Purrello8Alessandro D’Urso9Dipartimento di Scienze Chimiche, Università degli Studi di Catania, Viale Andrea Doria, 6 95125 Catania, ItalyDipartimento di Scienze Chimiche, Università degli Studi di Catania, Viale Andrea Doria, 6 95125 Catania, ItalyLaboratory of Photochemistry, Dipartimento di Scienze del Farmaco, Università degli Studi di Catania, Viale Andrea Doria, 6 95125 Catania, ItalyDipartimento di Scienze Chimiche, Università degli Studi di Catania, Viale Andrea Doria, 6 95125 Catania, ItalyDipartimento di Scienze Chimiche, Università degli Studi di Catania, Viale Andrea Doria, 6 95125 Catania, ItalyEnvironmental and Food Hygiene Laboratory (LIAA), Department of Medical, Surgery Sciences and Advanced Technologies “G.F. Ingrassia”, University of Catania, Via Santa Sofia 87, 95123 Catania, ItalyDipartimento di Scienze Chimiche, Università degli Studi di Catania, Viale Andrea Doria, 6 95125 Catania, ItalyEnvironmental and Food Hygiene Laboratory (LIAA), Department of Medical, Surgery Sciences and Advanced Technologies “G.F. Ingrassia”, University of Catania, Via Santa Sofia 87, 95123 Catania, ItalyDipartimento di Scienze Chimiche, Università degli Studi di Catania, Viale Andrea Doria, 6 95125 Catania, ItalyDipartimento di Scienze Chimiche, Università degli Studi di Catania, Viale Andrea Doria, 6 95125 Catania, ItalyAntibiotics represent essential drugs to contrast the insurgence of bacterial infections in humans and animals. Their extensive use in livestock farming, including aquaculture, has improved production performances and food safety. However, their overuse can implicate a risk of water pollution and related antimicrobial resistance. Consequently, innovative strategies for successfully removing antibiotic contaminants have to be advanced to protect human health. Among them, photodegradation TiO<sub>2</sub>-driven under solar irradiation appears not only as a promising method, but also a sustainable pathway. Hence, we evaluated several composite TiO<sub>2</sub> powders with H<sub>2</sub>TCPP, CuTCPP, ZnTCPP, and SnT4 porphyrin for this scope in order to explore the effect of porphyrins sensitization on titanium dioxide. The synthesis was realized through a fully non-covalent functionalization in water at room conditions. The efficacy of obtained composite materials was also tested in photodegrading oxolinic acid and oxytetracycline in aqueous solution at micromolar concentrations. Under simulated solar irradiation, TiO<sub>2</sub> functionalized with CuTCPP has shown encouraging results in the removal of oxytetracycline from water, by opening the way as new approaches to struggle against antibiotic’s pollution and, finally, to represent a new valuable tool of public health.https://www.mdpi.com/1422-0067/21/11/3775TiO<sub>2</sub>porphyrinantibioticphotocatalysisnoncovalent functionalizationrisk management |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Massimiliano Gaeta Giuseppe Sanfilippo Aurore Fraix Giuseppe Sortino Matteo Barcellona Gea Oliveri Conti Maria Elena Fragalà Margherita Ferrante Roberto Purrello Alessandro D’Urso |
spellingShingle |
Massimiliano Gaeta Giuseppe Sanfilippo Aurore Fraix Giuseppe Sortino Matteo Barcellona Gea Oliveri Conti Maria Elena Fragalà Margherita Ferrante Roberto Purrello Alessandro D’Urso Photodegradation of Antibiotics by Noncovalent Porphyrin-Functionalized TiO<sub>2</sub> in Water for the Bacterial Antibiotic Resistance Risk Management International Journal of Molecular Sciences TiO<sub>2</sub> porphyrin antibiotic photocatalysis noncovalent functionalization risk management |
author_facet |
Massimiliano Gaeta Giuseppe Sanfilippo Aurore Fraix Giuseppe Sortino Matteo Barcellona Gea Oliveri Conti Maria Elena Fragalà Margherita Ferrante Roberto Purrello Alessandro D’Urso |
author_sort |
Massimiliano Gaeta |
title |
Photodegradation of Antibiotics by Noncovalent Porphyrin-Functionalized TiO<sub>2</sub> in Water for the Bacterial Antibiotic Resistance Risk Management |
title_short |
Photodegradation of Antibiotics by Noncovalent Porphyrin-Functionalized TiO<sub>2</sub> in Water for the Bacterial Antibiotic Resistance Risk Management |
title_full |
Photodegradation of Antibiotics by Noncovalent Porphyrin-Functionalized TiO<sub>2</sub> in Water for the Bacterial Antibiotic Resistance Risk Management |
title_fullStr |
Photodegradation of Antibiotics by Noncovalent Porphyrin-Functionalized TiO<sub>2</sub> in Water for the Bacterial Antibiotic Resistance Risk Management |
title_full_unstemmed |
Photodegradation of Antibiotics by Noncovalent Porphyrin-Functionalized TiO<sub>2</sub> in Water for the Bacterial Antibiotic Resistance Risk Management |
title_sort |
photodegradation of antibiotics by noncovalent porphyrin-functionalized tio<sub>2</sub> in water for the bacterial antibiotic resistance risk management |
publisher |
MDPI AG |
series |
International Journal of Molecular Sciences |
issn |
1661-6596 1422-0067 |
publishDate |
2020-05-01 |
description |
Antibiotics represent essential drugs to contrast the insurgence of bacterial infections in humans and animals. Their extensive use in livestock farming, including aquaculture, has improved production performances and food safety. However, their overuse can implicate a risk of water pollution and related antimicrobial resistance. Consequently, innovative strategies for successfully removing antibiotic contaminants have to be advanced to protect human health. Among them, photodegradation TiO<sub>2</sub>-driven under solar irradiation appears not only as a promising method, but also a sustainable pathway. Hence, we evaluated several composite TiO<sub>2</sub> powders with H<sub>2</sub>TCPP, CuTCPP, ZnTCPP, and SnT4 porphyrin for this scope in order to explore the effect of porphyrins sensitization on titanium dioxide. The synthesis was realized through a fully non-covalent functionalization in water at room conditions. The efficacy of obtained composite materials was also tested in photodegrading oxolinic acid and oxytetracycline in aqueous solution at micromolar concentrations. Under simulated solar irradiation, TiO<sub>2</sub> functionalized with CuTCPP has shown encouraging results in the removal of oxytetracycline from water, by opening the way as new approaches to struggle against antibiotic’s pollution and, finally, to represent a new valuable tool of public health. |
topic |
TiO<sub>2</sub> porphyrin antibiotic photocatalysis noncovalent functionalization risk management |
url |
https://www.mdpi.com/1422-0067/21/11/3775 |
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