Crystal structure of 3,4-dichloroanilinium hydrogen phthalate
In the title salt, C6H6Cl2N+·C8H5O4−, the carboxylic acid and carboxylate groups of the anion form dihedral angles of 20.79 (19) and 74.76 (14)°, respectively, with the plane of the benzene ring. In the crystal, molecules are assembled into a two-dimensional polymeric network parallel to (100) via N...
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International Union of Crystallography
2015-07-01
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| Series: | Acta Crystallographica Section E: Crystallographic Communications |
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| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2056989015010300 |
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doaj-07bdd09cf514489695078d976a97e6e32020-11-24T21:40:21ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902015-07-01717o446o44610.1107/S2056989015010300gk2633Crystal structure of 3,4-dichloroanilinium hydrogen phthalateMuhammad Shahid0Muhammad Nawaz Tahir1Muhammad Salim2Munawar Ali Munawar3Department of Chemistry, University of the Punjab, Lahore, Punjab, PakistanDepartment of Physics, University of Sargodha, Sargodha, Punjab, PakistanDepartment of Chemistry, University of the Punjab, Lahore, Punjab, PakistanDepartment of Chemistry, University of the Punjab, Lahore, Punjab, PakistanIn the title salt, C6H6Cl2N+·C8H5O4−, the carboxylic acid and carboxylate groups of the anion form dihedral angles of 20.79 (19) and 74.76 (14)°, respectively, with the plane of the benzene ring. In the crystal, molecules are assembled into a two-dimensional polymeric network parallel to (100) via N—H...O and O—H...O hydrogen bonds. In addition, within the layer, there are π–π stacking interactions between the benzene rings of the cation and the anion [centroid–centroid distance = 3.6794 (17) Å]. A weak C—H...O interaction is also observed.http://scripts.iucr.org/cgi-bin/paper?S2056989015010300crystal structurehydrogen phthalatehydrogen bondingπ–π stacking interactions |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Muhammad Shahid Muhammad Nawaz Tahir Muhammad Salim Munawar Ali Munawar |
| spellingShingle |
Muhammad Shahid Muhammad Nawaz Tahir Muhammad Salim Munawar Ali Munawar Crystal structure of 3,4-dichloroanilinium hydrogen phthalate Acta Crystallographica Section E: Crystallographic Communications crystal structure hydrogen phthalate hydrogen bonding π–π stacking interactions |
| author_facet |
Muhammad Shahid Muhammad Nawaz Tahir Muhammad Salim Munawar Ali Munawar |
| author_sort |
Muhammad Shahid |
| title |
Crystal structure of 3,4-dichloroanilinium hydrogen phthalate |
| title_short |
Crystal structure of 3,4-dichloroanilinium hydrogen phthalate |
| title_full |
Crystal structure of 3,4-dichloroanilinium hydrogen phthalate |
| title_fullStr |
Crystal structure of 3,4-dichloroanilinium hydrogen phthalate |
| title_full_unstemmed |
Crystal structure of 3,4-dichloroanilinium hydrogen phthalate |
| title_sort |
crystal structure of 3,4-dichloroanilinium hydrogen phthalate |
| publisher |
International Union of Crystallography |
| series |
Acta Crystallographica Section E: Crystallographic Communications |
| issn |
2056-9890 |
| publishDate |
2015-07-01 |
| description |
In the title salt, C6H6Cl2N+·C8H5O4−, the carboxylic acid and carboxylate groups of the anion form dihedral angles of 20.79 (19) and 74.76 (14)°, respectively, with the plane of the benzene ring. In the crystal, molecules are assembled into a two-dimensional polymeric network parallel to (100) via N—H...O and O—H...O hydrogen bonds. In addition, within the layer, there are π–π stacking interactions between the benzene rings of the cation and the anion [centroid–centroid distance = 3.6794 (17) Å]. A weak C—H...O interaction is also observed. |
| topic |
crystal structure hydrogen phthalate hydrogen bonding π–π stacking interactions |
| url |
http://scripts.iucr.org/cgi-bin/paper?S2056989015010300 |
| work_keys_str_mv |
AT muhammadshahid crystalstructureof34dichloroaniliniumhydrogenphthalate AT muhammadnawaztahir crystalstructureof34dichloroaniliniumhydrogenphthalate AT muhammadsalim crystalstructureof34dichloroaniliniumhydrogenphthalate AT munawaralimunawar crystalstructureof34dichloroaniliniumhydrogenphthalate |
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