In situ formation of mononuclear complexes by reaction-induced atomic dispersion of supported noble metal nanoparticles

Supported noble metal nanoclusters and single-metal-sites catalysts are inclined to aggregate into particles. Here, the authors report a general method with CO and CH3I to disperse the metal nanoparticles of Ru, Rh, Pd, Ag, Ir and Pt completely into single atoms with loading up to 5 wt%.

Bibliographic Details
Main Authors:	Siquan Feng, Xiangen Song, Yang Liu, Xiangsong Lin, Li Yan, Siyue Liu, Wenrui Dong, Xueming Yang, Zheng Jiang, Yunjie Ding
Format:	Article
Language:	English
Published:	Nature Publishing Group 2019-11-01
Series:	Nature Communications
Online Access:	https://doi.org/10.1038/s41467-019-12965-1

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spelling	doaj-07cab734fa41491983886b38a3cc8cb92021-05-11T12:34:36ZengNature Publishing GroupNature Communications2041-17232019-11-011011910.1038/s41467-019-12965-1In situ formation of mononuclear complexes by reaction-induced atomic dispersion of supported noble metal nanoparticlesSiquan Feng0Xiangen Song1Yang Liu2Xiangsong Lin3Li Yan4Siyue Liu5Wenrui Dong6Xueming Yang7Zheng Jiang8Yunjie Ding9Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of SciencesDalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of SciencesUniversity of Chinese Academy of SciencesSchool of Materials and Textile Engineering, Jiaxing UniversityDalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of SciencesState Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of SciencesState Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of SciencesState Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of SciencesShanghai Synchrotron Radiation Facility, Shanghai Institute of Applied Physics, and shanghai Advanced Research Institute, Chinese Academy of SciencesDalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of SciencesSupported noble metal nanoclusters and single-metal-sites catalysts are inclined to aggregate into particles. Here, the authors report a general method with CO and CH3I to disperse the metal nanoparticles of Ru, Rh, Pd, Ag, Ir and Pt completely into single atoms with loading up to 5 wt%.https://doi.org/10.1038/s41467-019-12965-1
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	Siquan Feng Xiangen Song Yang Liu Xiangsong Lin Li Yan Siyue Liu Wenrui Dong Xueming Yang Zheng Jiang Yunjie Ding
spellingShingle	Siquan Feng Xiangen Song Yang Liu Xiangsong Lin Li Yan Siyue Liu Wenrui Dong Xueming Yang Zheng Jiang Yunjie Ding In situ formation of mononuclear complexes by reaction-induced atomic dispersion of supported noble metal nanoparticles Nature Communications
author_facet	Siquan Feng Xiangen Song Yang Liu Xiangsong Lin Li Yan Siyue Liu Wenrui Dong Xueming Yang Zheng Jiang Yunjie Ding
author_sort	Siquan Feng
title	In situ formation of mononuclear complexes by reaction-induced atomic dispersion of supported noble metal nanoparticles
title_short	In situ formation of mononuclear complexes by reaction-induced atomic dispersion of supported noble metal nanoparticles
title_full	In situ formation of mononuclear complexes by reaction-induced atomic dispersion of supported noble metal nanoparticles
title_fullStr	In situ formation of mononuclear complexes by reaction-induced atomic dispersion of supported noble metal nanoparticles
title_full_unstemmed	In situ formation of mononuclear complexes by reaction-induced atomic dispersion of supported noble metal nanoparticles
title_sort	in situ formation of mononuclear complexes by reaction-induced atomic dispersion of supported noble metal nanoparticles
publisher	Nature Publishing Group
series	Nature Communications
issn	2041-1723
publishDate	2019-11-01
description	Supported noble metal nanoclusters and single-metal-sites catalysts are inclined to aggregate into particles. Here, the authors report a general method with CO and CH3I to disperse the metal nanoparticles of Ru, Rh, Pd, Ag, Ir and Pt completely into single atoms with loading up to 5 wt%.
url	https://doi.org/10.1038/s41467-019-12965-1
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In situ formation of mononuclear complexes by reaction-induced atomic dispersion of supported noble metal nanoparticles

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