Dimer rattling mode induced low thermal conductivity in an excellent acoustic conductor
CuP2 has a puzzling thermal transport behavior, with low thermal conductivity but quite large mean sound speeds. Here, the authors conduct a systematical study of the atomic structure and lattice dynamics of CuP2 to reveal the origin, finding a dimer rattling behavior.
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doaj-07dd92d3630341c8b3bde96253f2c8be2021-05-11T08:29:42ZengNature Publishing GroupNature Communications2041-17232020-10-011111810.1038/s41467-020-19044-wDimer rattling mode induced low thermal conductivity in an excellent acoustic conductorJi Qi0Baojuan Dong1Zhe Zhang2Zhao Zhang3Yanna Chen4Qiang Zhang5Sergey Danilkin6Xi Chen7Jiaming He8Liangwei Fu9Xiaoming Jiang10Guozhi Chai11Satoshi Hiroi12Koji Ohara13Zongteng Zhang14Weijun Ren15Teng Yang16Jianshi Zhou17Sakata Osami18Jiaqing He19Dehong Yu20Bing Li21Zhidong Zhang22Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of SciencesShenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of SciencesShenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of SciencesShenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of SciencesSynchrontron X-ray station at SPring-8, Research Network and Facility Services Division, National Institute for Materials Science (NIMS)Spallation Neutron Source, Oak Ridge National LaboratoryAustralian Nuclear Science and Technology OrganisationDepartment of Mechanical Engineering, University of Texas at AustinDepartment of Mechanical Engineering, University of Texas at AustinDepartment of Physics, Southern University of Science and TechnologyState Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of SciencesKey Lab for Magnetism and Magnetic Materials of the Ministry of Education, Lanzhou UniversitySynchrontron X-ray station at SPring-8, Research Network and Facility Services Division, National Institute for Materials Science (NIMS)SPring-8, Diffraction and Scattering Division, Japan Synchrotron Radiation Research InstituteShenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of SciencesShenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of SciencesShenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of SciencesDepartment of Mechanical Engineering, University of Texas at AustinSynchrontron X-ray station at SPring-8, Research Network and Facility Services Division, National Institute for Materials Science (NIMS)Department of Physics, Southern University of Science and TechnologyAustralian Nuclear Science and Technology OrganisationShenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of SciencesShenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of SciencesCuP2 has a puzzling thermal transport behavior, with low thermal conductivity but quite large mean sound speeds. Here, the authors conduct a systematical study of the atomic structure and lattice dynamics of CuP2 to reveal the origin, finding a dimer rattling behavior.https://doi.org/10.1038/s41467-020-19044-w |
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DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Ji Qi Baojuan Dong Zhe Zhang Zhao Zhang Yanna Chen Qiang Zhang Sergey Danilkin Xi Chen Jiaming He Liangwei Fu Xiaoming Jiang Guozhi Chai Satoshi Hiroi Koji Ohara Zongteng Zhang Weijun Ren Teng Yang Jianshi Zhou Sakata Osami Jiaqing He Dehong Yu Bing Li Zhidong Zhang |
spellingShingle |
Ji Qi Baojuan Dong Zhe Zhang Zhao Zhang Yanna Chen Qiang Zhang Sergey Danilkin Xi Chen Jiaming He Liangwei Fu Xiaoming Jiang Guozhi Chai Satoshi Hiroi Koji Ohara Zongteng Zhang Weijun Ren Teng Yang Jianshi Zhou Sakata Osami Jiaqing He Dehong Yu Bing Li Zhidong Zhang Dimer rattling mode induced low thermal conductivity in an excellent acoustic conductor Nature Communications |
author_facet |
Ji Qi Baojuan Dong Zhe Zhang Zhao Zhang Yanna Chen Qiang Zhang Sergey Danilkin Xi Chen Jiaming He Liangwei Fu Xiaoming Jiang Guozhi Chai Satoshi Hiroi Koji Ohara Zongteng Zhang Weijun Ren Teng Yang Jianshi Zhou Sakata Osami Jiaqing He Dehong Yu Bing Li Zhidong Zhang |
author_sort |
Ji Qi |
title |
Dimer rattling mode induced low thermal conductivity in an excellent acoustic conductor |
title_short |
Dimer rattling mode induced low thermal conductivity in an excellent acoustic conductor |
title_full |
Dimer rattling mode induced low thermal conductivity in an excellent acoustic conductor |
title_fullStr |
Dimer rattling mode induced low thermal conductivity in an excellent acoustic conductor |
title_full_unstemmed |
Dimer rattling mode induced low thermal conductivity in an excellent acoustic conductor |
title_sort |
dimer rattling mode induced low thermal conductivity in an excellent acoustic conductor |
publisher |
Nature Publishing Group |
series |
Nature Communications |
issn |
2041-1723 |
publishDate |
2020-10-01 |
description |
CuP2 has a puzzling thermal transport behavior, with low thermal conductivity but quite large mean sound speeds. Here, the authors conduct a systematical study of the atomic structure and lattice dynamics of CuP2 to reveal the origin, finding a dimer rattling behavior. |
url |
https://doi.org/10.1038/s41467-020-19044-w |
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