Dibromido(2,2′:6′,2′′-terpyridine-κ3N,N′,N′′)zinc(II)
In the title compound, [ZnBr2(C15H11N3)], the ZnII ion is five-coordinated by the three N atoms from a 2,2′:6′,2′′-terpyridine ligand (terpy) and two bromide anions in a distorted trigonal bipyramidal configuration. Each molecule is situated on...
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International Union of Crystallography
2009-06-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809019266 |
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doaj-082df437575b4800b9a58d0b7fcf599f2020-11-24T21:37:54ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-06-01656m693m69310.1107/S1600536809019266Dibromido(2,2′:6′,2′′-terpyridine-κ3N,N′,N′′)zinc(II)Qing-Lan ZhaoGuo-Peng LiIn the title compound, [ZnBr2(C15H11N3)], the ZnII ion is five-coordinated by the three N atoms from a 2,2′:6′,2′′-terpyridine ligand (terpy) and two bromide anions in a distorted trigonal bipyramidal configuration. Each molecule is situated on a twofold rotational axis that passes through the ZnII ion and the central ring of the terpy ligand. In the crystal structure, aromatic π–π interactions between terpy ligands [centroid–centroid distances = 3.6265 (9) Å] link molecules into stacks propagated in the [001] direction. http://scripts.iucr.org/cgi-bin/paper?S1600536809019266 |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Qing-Lan Zhao Guo-Peng Li |
| spellingShingle |
Qing-Lan Zhao Guo-Peng Li Dibromido(2,2′:6′,2′′-terpyridine-κ3N,N′,N′′)zinc(II) Acta Crystallographica Section E |
| author_facet |
Qing-Lan Zhao Guo-Peng Li |
| author_sort |
Qing-Lan Zhao |
| title |
Dibromido(2,2′:6′,2′′-terpyridine-κ3N,N′,N′′)zinc(II) |
| title_short |
Dibromido(2,2′:6′,2′′-terpyridine-κ3N,N′,N′′)zinc(II) |
| title_full |
Dibromido(2,2′:6′,2′′-terpyridine-κ3N,N′,N′′)zinc(II) |
| title_fullStr |
Dibromido(2,2′:6′,2′′-terpyridine-κ3N,N′,N′′)zinc(II) |
| title_full_unstemmed |
Dibromido(2,2′:6′,2′′-terpyridine-κ3N,N′,N′′)zinc(II) |
| title_sort |
dibromido(2,2′:6′,2′′-terpyridine-κ3n,n′,n′′)zinc(ii) |
| publisher |
International Union of Crystallography |
| series |
Acta Crystallographica Section E |
| issn |
1600-5368 |
| publishDate |
2009-06-01 |
| description |
In the title compound, [ZnBr2(C15H11N3)], the ZnII ion is five-coordinated by the three N atoms from a 2,2′:6′,2′′-terpyridine ligand (terpy) and two bromide anions in a distorted trigonal bipyramidal configuration. Each molecule is situated on a twofold rotational axis that passes through the ZnII ion and the central ring of the terpy ligand. In the crystal structure, aromatic π–π interactions between terpy ligands [centroid–centroid distances = 3.6265 (9) Å] link molecules into stacks propagated in the [001] direction. |
| url |
http://scripts.iucr.org/cgi-bin/paper?S1600536809019266 |
| work_keys_str_mv |
AT qinglanzhao dibromido22amp82426amp82422amp8242amp8242terpyridineamp9543nnamp8242namp8242amp8242zincii AT guopengli dibromido22amp82426amp82422amp8242amp8242terpyridineamp9543nnamp8242namp8242amp8242zincii |
| _version_ |
1725936539283750912 |