Bis[2,3-bis(pyridin-2-yl)pyrazine-κ2N2,N3]palladium(II) dinitrate acetonitrile monosolvate

The title compound, [Pd(C14H10N4)2](NO3)2·CH3CN, consists of a cationic PdII complex, two anions and one lattice solvent molecule, all in general positions. In the complex, the PdII cation is four-coordinated in a slightly distorted square-planar geometry defined by the four N atoms of two bidentate...

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Main Author: Kwang Ha
Format: Article
Language:English
Published: International Union of Crystallography 2021-02-01
Series:IUCrData
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Online Access:http://scripts.iucr.org/cgi-bin/paper?S241431462100153X
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spelling doaj-083a34194aa846a5a5c197e32d2aa4752021-04-22T11:00:42ZengInternational Union of CrystallographyIUCrData2414-31462021-02-0162x21015310.1107/S241431462100153Xbh4059Bis[2,3-bis(pyridin-2-yl)pyrazine-κ2N2,N3]palladium(II) dinitrate acetonitrile monosolvateKwang Ha0Chonnam National University, School of Chemical Engineering, Research Institute of Catalysis, Gwangju, Republic of KoreaThe title compound, [Pd(C14H10N4)2](NO3)2·CH3CN, consists of a cationic PdII complex, two anions and one lattice solvent molecule, all in general positions. In the complex, the PdII cation is four-coordinated in a slightly distorted square-planar geometry defined by the four N atoms of two bidentate 2,3-di-2-pyridylpyrazine ligands. The complex, anions and solvent molecule are linked by weak C—H...O intermolecular hydrogen bonds. In the crystal, the complex molecules are stacked in columns along the a axis.http://scripts.iucr.org/cgi-bin/paper?S241431462100153Xcrystal structurepalladium(ii) complexsquare-planar structure2,3-di-2-pyridylpyrazine
collection DOAJ
language English
format Article
sources DOAJ
author Kwang Ha
spellingShingle Kwang Ha
Bis[2,3-bis(pyridin-2-yl)pyrazine-κ2N2,N3]palladium(II) dinitrate acetonitrile monosolvate
IUCrData
crystal structure
palladium(ii) complex
square-planar structure
2,3-di-2-pyridylpyrazine
author_facet Kwang Ha
author_sort Kwang Ha
title Bis[2,3-bis(pyridin-2-yl)pyrazine-κ2N2,N3]palladium(II) dinitrate acetonitrile monosolvate
title_short Bis[2,3-bis(pyridin-2-yl)pyrazine-κ2N2,N3]palladium(II) dinitrate acetonitrile monosolvate
title_full Bis[2,3-bis(pyridin-2-yl)pyrazine-κ2N2,N3]palladium(II) dinitrate acetonitrile monosolvate
title_fullStr Bis[2,3-bis(pyridin-2-yl)pyrazine-κ2N2,N3]palladium(II) dinitrate acetonitrile monosolvate
title_full_unstemmed Bis[2,3-bis(pyridin-2-yl)pyrazine-κ2N2,N3]palladium(II) dinitrate acetonitrile monosolvate
title_sort bis[2,3-bis(pyridin-2-yl)pyrazine-κ2n2,n3]palladium(ii) dinitrate acetonitrile monosolvate
publisher International Union of Crystallography
series IUCrData
issn 2414-3146
publishDate 2021-02-01
description The title compound, [Pd(C14H10N4)2](NO3)2·CH3CN, consists of a cationic PdII complex, two anions and one lattice solvent molecule, all in general positions. In the complex, the PdII cation is four-coordinated in a slightly distorted square-planar geometry defined by the four N atoms of two bidentate 2,3-di-2-pyridylpyrazine ligands. The complex, anions and solvent molecule are linked by weak C—H...O intermolecular hydrogen bonds. In the crystal, the complex molecules are stacked in columns along the a axis.
topic crystal structure
palladium(ii) complex
square-planar structure
2,3-di-2-pyridylpyrazine
url http://scripts.iucr.org/cgi-bin/paper?S241431462100153X
work_keys_str_mv AT kwangha bis23bispyridin2ylpyrazinek2n2n3palladiumiidinitrateacetonitrilemonosolvate
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