Model Matematik Reduksi Thorium dalam Proses Elektrokoagulasi

• Main Authors: Prayitno, Vemi Ridantami
• Format: Article
• Language: English
• Published: Center for Nuclear Minerals Technology 2017-11-01
• Series: Eksplorium: Buletin Pusat Pengembangan Bahan Galian Nuklir
• Subjects: kinetika; elektrokoagulasi; plat aluminium; thorium
• Online Access: http://jurnal.batan.go.id/index.php/eksplorium/article/view/3566/pdf

Thorium reduction by electrocoagulation has been conducted on radioactive waste with thorium contaminant grade of 5x10-4Kg/l through a batch system using aluminium electrodes. This study aims to determine a mathematical model of thorium reduction through speed reaction, constante reaction rate and reaction order which are affected by electrocoagulation process parameters like voltage, time, electrode distance, and pH. The research results the optimum voltage condition at 12.5 V at 1 cm electrode spacing, pH 7, and 30 minutes of processing time with 99.6 % efficiency. Prediction on thorium decline rate constante is obtained through mathematic integral method calculation. The research results thorium decline rate is following second order constante with its value at 5x10-3KgL-1min-1.