Synthesis, Crystal Structure, and Catalytic Activity of a Calcium(II) Complex with 4-Formylbenzene-1,3-disulfonate-isonicotinic Acid Hydrazone
A new calcium(II) complex was synthesized by one-pot synthesis method from disodium 4-formylbenzene-1,3-disulfonate, isonicotinic acid hydrazide and Ca(ClO4)2•2H2O. The structure of calcium(II) complex was determined by elemental analysis, IR and single crystal X-ray diffraction. The results show th...
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doaj-094854d2406a42f58f4365bd9e963f662021-05-02T00:49:20ZengDiponegoro UniversityBulletin of Chemical Reaction Engineering & Catalysis1978-29932018-12-0113342943510.9767/bcrec.13.3.1961.429-4351435Synthesis, Crystal Structure, and Catalytic Activity of a Calcium(II) Complex with 4-Formylbenzene-1,3-disulfonate-isonicotinic Acid HydrazoneXi-Shi Tai0Peng-Fei Li1Li-Li Liu2College of Chemistry and Chemical Engineering, Weifang University , Weifang 261061, ChinaCollege of Chemical Engineering, Qingdao University of Science and Technology , Qingdao 266061, ChinaCollege of Chemistry and Chemical Engineering, Weifang University , Weifang 261061, ChinaA new calcium(II) complex was synthesized by one-pot synthesis method from disodium 4-formylbenzene-1,3-disulfonate, isonicotinic acid hydrazide and Ca(ClO4)2•2H2O. The structure of calcium(II) complex was determined by elemental analysis, IR and single crystal X-ray diffraction. The results show that the Ca(II) complex molecules form 3D network structure by the interactions of π-π stacking and hydrogen bonds. The Ca(II) complex catalyst could efficiently catalyse oxidation of benzylic alcohol with good conversion of benzyl alcohol (78 %) and excellent selectivity of benzaldehyde (98 %).Copyright © 2018 BCREC Group. All rights reserved. Received: 13rd December 2017; Revised: 23rd May 2018; Accepted: 23rd May 2018 How to Cite: Tai, X.S., Li, P.F., Liu, L.L. (2018). Synthesis, Crystal Structure, and Catalytic Activity of a Calcium(II) Complex with 4-Formylbenzene-1,3-disulfonate-isonicotinic Acid Hydrazone. Bulletin of Chemical Reaction Engineering & Catalysis, 13 (3): 429-435 (doi:10.9767/bcrec.13.3.1961.429-435) Permalink/DOI: https://doi.org/10.9767/bcrec.13.3.1961.429-435https://ejournal2.undip.ac.id/index.php/bcrec/article/view/1961ca(ii) complex catalystsynthesisstructural characterizationcatalytic activity |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Xi-Shi Tai Peng-Fei Li Li-Li Liu |
spellingShingle |
Xi-Shi Tai Peng-Fei Li Li-Li Liu Synthesis, Crystal Structure, and Catalytic Activity of a Calcium(II) Complex with 4-Formylbenzene-1,3-disulfonate-isonicotinic Acid Hydrazone Bulletin of Chemical Reaction Engineering & Catalysis ca(ii) complex catalyst synthesis structural characterization catalytic activity |
author_facet |
Xi-Shi Tai Peng-Fei Li Li-Li Liu |
author_sort |
Xi-Shi Tai |
title |
Synthesis, Crystal Structure, and Catalytic Activity of a Calcium(II) Complex with 4-Formylbenzene-1,3-disulfonate-isonicotinic Acid Hydrazone |
title_short |
Synthesis, Crystal Structure, and Catalytic Activity of a Calcium(II) Complex with 4-Formylbenzene-1,3-disulfonate-isonicotinic Acid Hydrazone |
title_full |
Synthesis, Crystal Structure, and Catalytic Activity of a Calcium(II) Complex with 4-Formylbenzene-1,3-disulfonate-isonicotinic Acid Hydrazone |
title_fullStr |
Synthesis, Crystal Structure, and Catalytic Activity of a Calcium(II) Complex with 4-Formylbenzene-1,3-disulfonate-isonicotinic Acid Hydrazone |
title_full_unstemmed |
Synthesis, Crystal Structure, and Catalytic Activity of a Calcium(II) Complex with 4-Formylbenzene-1,3-disulfonate-isonicotinic Acid Hydrazone |
title_sort |
synthesis, crystal structure, and catalytic activity of a calcium(ii) complex with 4-formylbenzene-1,3-disulfonate-isonicotinic acid hydrazone |
publisher |
Diponegoro University |
series |
Bulletin of Chemical Reaction Engineering & Catalysis |
issn |
1978-2993 |
publishDate |
2018-12-01 |
description |
A new calcium(II) complex was synthesized by one-pot synthesis method from disodium 4-formylbenzene-1,3-disulfonate, isonicotinic acid hydrazide and Ca(ClO4)2•2H2O. The structure of calcium(II) complex was determined by elemental analysis, IR and single crystal X-ray diffraction. The results show that the Ca(II) complex molecules form 3D network structure by the interactions of π-π stacking and hydrogen bonds. The Ca(II) complex catalyst could efficiently catalyse oxidation of benzylic alcohol with good conversion of benzyl alcohol (78 %) and excellent selectivity of benzaldehyde (98 %).Copyright © 2018 BCREC Group. All rights reserved.
Received: 13rd December 2017; Revised: 23rd May 2018; Accepted: 23rd May 2018
How to Cite: Tai, X.S., Li, P.F., Liu, L.L. (2018). Synthesis, Crystal Structure, and Catalytic Activity of a Calcium(II) Complex with 4-Formylbenzene-1,3-disulfonate-isonicotinic Acid Hydrazone. Bulletin of Chemical Reaction Engineering & Catalysis, 13 (3): 429-435 (doi:10.9767/bcrec.13.3.1961.429-435)
Permalink/DOI: https://doi.org/10.9767/bcrec.13.3.1961.429-435 |
topic |
ca(ii) complex catalyst synthesis structural characterization catalytic activity |
url |
https://ejournal2.undip.ac.id/index.php/bcrec/article/view/1961 |
work_keys_str_mv |
AT xishitai synthesiscrystalstructureandcatalyticactivityofacalciumiicomplexwith4formylbenzene13disulfonateisonicotinicacidhydrazone AT pengfeili synthesiscrystalstructureandcatalyticactivityofacalciumiicomplexwith4formylbenzene13disulfonateisonicotinicacidhydrazone AT lililiu synthesiscrystalstructureandcatalyticactivityofacalciumiicomplexwith4formylbenzene13disulfonateisonicotinicacidhydrazone |
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1721496715560747008 |