The crystal structure of (E)-2-ethyl-N-(4-nitrobenzylidene)aniline: three-dimensional supramolecular assembly mediated by C—H...O hydrogen bonds and nitro...π(arene) interactions

In the molecule of the title compound, C15H14N2O2, the 2-ethylphenyl group is disordered over two sets of atomic sites having occupancies of 0.515 (19) and 0.485 (19), and the dihedral angle between the two partial-occupancy aryl rings is 6(2)°. A combination of C—H...O hydrogen bonds and nitro...π(...

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Main Authors:	Marisiddaiah Girisha, Belakavadi K. Sagar, Hemmige S. Yathirajan, Ravindranath S. Rathore, Christopher Glidewell
Format:	Article
Language:	English
Published:	International Union of Crystallography 2018-08-01
Series:	Acta Crystallographica Section E: Crystallographic Communications
Subjects:	Schiff bases crystal structure disorder molecular conformation hydrogen bonding nitro...π(arene) interactions supramolecular assembly
Online Access:	http://scripts.iucr.org/cgi-bin/paper?S2056989018009544

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spelling	doaj-09a5e408a7a246a6bc75f9de285c46972020-11-24T22:51:14ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902018-08-017481071107410.1107/S2056989018009544zl2733The crystal structure of (E)-2-ethyl-N-(4-nitrobenzylidene)aniline: three-dimensional supramolecular assembly mediated by C—H...O hydrogen bonds and nitro...π(arene) interactionsMarisiddaiah Girisha0Belakavadi K. Sagar1Hemmige S. Yathirajan2Ravindranath S. Rathore3Christopher Glidewell4Department of Studies in Chemistry, University of Mysore, Manasagangotri, Mysuru 570 006, IndiaDepartment of Studies in Chemistry, University of Mysore, Manasagangotri, Mysuru 570 006, IndiaDepartment of Studies in Chemistry, University of Mysore, Manasagangotri, Mysuru 570 006, IndiaCentre for Biological Sciences (Bioinformatics), School of Earth, Biological and Environmental Sciences, Central University of South Bihar, Patna 800 014, IndiaSchool of Chemistry, University of St Andrews, St Andrews, Fife KY16 9ST, UKIn the molecule of the title compound, C15H14N2O2, the 2-ethylphenyl group is disordered over two sets of atomic sites having occupancies of 0.515 (19) and 0.485 (19), and the dihedral angle between the two partial-occupancy aryl rings is 6(2)°. A combination of C—H...O hydrogen bonds and nitro...π(arene) interactions links the molecules into a continuous three-dimensional framework structure. Comparisons are made with the structures of some related compounds.http://scripts.iucr.org/cgi-bin/paper?S2056989018009544Schiff basescrystal structuredisordermolecular conformationhydrogen bondingnitro...π(arene) interactionssupramolecular assembly
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	Marisiddaiah Girisha Belakavadi K. Sagar Hemmige S. Yathirajan Ravindranath S. Rathore Christopher Glidewell
spellingShingle	Marisiddaiah Girisha Belakavadi K. Sagar Hemmige S. Yathirajan Ravindranath S. Rathore Christopher Glidewell The crystal structure of (E)-2-ethyl-N-(4-nitrobenzylidene)aniline: three-dimensional supramolecular assembly mediated by C—H...O hydrogen bonds and nitro...π(arene) interactions Acta Crystallographica Section E: Crystallographic Communications Schiff bases crystal structure disorder molecular conformation hydrogen bonding nitro...π(arene) interactions supramolecular assembly
author_facet	Marisiddaiah Girisha Belakavadi K. Sagar Hemmige S. Yathirajan Ravindranath S. Rathore Christopher Glidewell
author_sort	Marisiddaiah Girisha
title	The crystal structure of (E)-2-ethyl-N-(4-nitrobenzylidene)aniline: three-dimensional supramolecular assembly mediated by C—H...O hydrogen bonds and nitro...π(arene) interactions
title_short	The crystal structure of (E)-2-ethyl-N-(4-nitrobenzylidene)aniline: three-dimensional supramolecular assembly mediated by C—H...O hydrogen bonds and nitro...π(arene) interactions
title_full	The crystal structure of (E)-2-ethyl-N-(4-nitrobenzylidene)aniline: three-dimensional supramolecular assembly mediated by C—H...O hydrogen bonds and nitro...π(arene) interactions
title_fullStr	The crystal structure of (E)-2-ethyl-N-(4-nitrobenzylidene)aniline: three-dimensional supramolecular assembly mediated by C—H...O hydrogen bonds and nitro...π(arene) interactions
title_full_unstemmed	The crystal structure of (E)-2-ethyl-N-(4-nitrobenzylidene)aniline: three-dimensional supramolecular assembly mediated by C—H...O hydrogen bonds and nitro...π(arene) interactions
title_sort	crystal structure of (e)-2-ethyl-n-(4-nitrobenzylidene)aniline: three-dimensional supramolecular assembly mediated by c—h...o hydrogen bonds and nitro...π(arene) interactions
publisher	International Union of Crystallography
series	Acta Crystallographica Section E: Crystallographic Communications
issn	2056-9890
publishDate	2018-08-01
description	In the molecule of the title compound, C15H14N2O2, the 2-ethylphenyl group is disordered over two sets of atomic sites having occupancies of 0.515 (19) and 0.485 (19), and the dihedral angle between the two partial-occupancy aryl rings is 6(2)°. A combination of C—H...O hydrogen bonds and nitro...π(arene) interactions links the molecules into a continuous three-dimensional framework structure. Comparisons are made with the structures of some related compounds.
topic	Schiff bases crystal structure disorder molecular conformation hydrogen bonding nitro...π(arene) interactions supramolecular assembly
url	http://scripts.iucr.org/cgi-bin/paper?S2056989018009544
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The crystal structure of (E)-2-ethyl-N-(4-nitrobenzylidene)aniline: three-dimensional supramolecular assembly mediated by C—H...O hydrogen bonds and nitro...π(arene) interactions

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