Comparison of Conformational Phase Behavior for Flexible and Semiflexible Polymers
We employ the recently introduced generalized microcanonical inflection point method for the statistical analysis of phase transitions in flexible and semiflexible polymers and study the impact of the bending stiffness upon the character and order of transitions between random-coil, globules, and ps...
Main Authors: | , |
---|---|
Format: | Article |
Language: | English |
Published: |
MDPI AG
2020-12-01
|
Series: | Polymers |
Subjects: | |
Online Access: | https://www.mdpi.com/2073-4360/12/12/3013 |
id |
doaj-0a88c196002c41b59f591cdc1f3e64f9 |
---|---|
record_format |
Article |
spelling |
doaj-0a88c196002c41b59f591cdc1f3e64f92020-12-17T00:05:32ZengMDPI AGPolymers2073-43602020-12-01123013301310.3390/polym12123013Comparison of Conformational Phase Behavior for Flexible and Semiflexible PolymersDilimulati Aierken0Michael Bachmann1Soft Matter Systems Research Group, Center for Simulational Physics, The University of Georgia, Athens, GA 30602, USASoft Matter Systems Research Group, Center for Simulational Physics, The University of Georgia, Athens, GA 30602, USAWe employ the recently introduced generalized microcanonical inflection point method for the statistical analysis of phase transitions in flexible and semiflexible polymers and study the impact of the bending stiffness upon the character and order of transitions between random-coil, globules, and pseudocrystalline conformations. The high-accuracy estimates of the microcanonical entropy and its derivatives required for this study were obtained by extensive replica-exchange Monte Carlo simulations. We observe that the transition behavior into the compact phases changes qualitatively with increasing bending stiffness. Whereas the <inline-formula><math display="inline"><semantics><mi>Θ</mi></semantics></math></inline-formula> collapse transition is less affected, the first-order liquid-solid transition characteristic for flexible polymers ceases to exist once bending effects dominate over attractive monomer-monomer interactions.https://www.mdpi.com/2073-4360/12/12/3013flexible polymerssemiflexible polymersconformational phasesphase transitionsMonte Carlo simulationsmicrocanonical analysis |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Dilimulati Aierken Michael Bachmann |
spellingShingle |
Dilimulati Aierken Michael Bachmann Comparison of Conformational Phase Behavior for Flexible and Semiflexible Polymers Polymers flexible polymers semiflexible polymers conformational phases phase transitions Monte Carlo simulations microcanonical analysis |
author_facet |
Dilimulati Aierken Michael Bachmann |
author_sort |
Dilimulati Aierken |
title |
Comparison of Conformational Phase Behavior for Flexible and Semiflexible Polymers |
title_short |
Comparison of Conformational Phase Behavior for Flexible and Semiflexible Polymers |
title_full |
Comparison of Conformational Phase Behavior for Flexible and Semiflexible Polymers |
title_fullStr |
Comparison of Conformational Phase Behavior for Flexible and Semiflexible Polymers |
title_full_unstemmed |
Comparison of Conformational Phase Behavior for Flexible and Semiflexible Polymers |
title_sort |
comparison of conformational phase behavior for flexible and semiflexible polymers |
publisher |
MDPI AG |
series |
Polymers |
issn |
2073-4360 |
publishDate |
2020-12-01 |
description |
We employ the recently introduced generalized microcanonical inflection point method for the statistical analysis of phase transitions in flexible and semiflexible polymers and study the impact of the bending stiffness upon the character and order of transitions between random-coil, globules, and pseudocrystalline conformations. The high-accuracy estimates of the microcanonical entropy and its derivatives required for this study were obtained by extensive replica-exchange Monte Carlo simulations. We observe that the transition behavior into the compact phases changes qualitatively with increasing bending stiffness. Whereas the <inline-formula><math display="inline"><semantics><mi>Θ</mi></semantics></math></inline-formula> collapse transition is less affected, the first-order liquid-solid transition characteristic for flexible polymers ceases to exist once bending effects dominate over attractive monomer-monomer interactions. |
topic |
flexible polymers semiflexible polymers conformational phases phase transitions Monte Carlo simulations microcanonical analysis |
url |
https://www.mdpi.com/2073-4360/12/12/3013 |
work_keys_str_mv |
AT dilimulatiaierken comparisonofconformationalphasebehaviorforflexibleandsemiflexiblepolymers AT michaelbachmann comparisonofconformationalphasebehaviorforflexibleandsemiflexiblepolymers |
_version_ |
1724380633124306944 |