Study on the structure-properties relationship of natural rubber/SiO2 composites modified by a novel multi-functional rubber agent
Vulcanization property and structure-properties relationship of natural rubber (NR)/silica (SiO2) composites modified by a novel multi-functional rubber agent, N-phenyl- N'-(γ-triethoxysilane)-propyl thiourea (STU), are investigated in detail. Results from the infrared spectroscopy (IR) and X-r...
Main Authors: | , , , , , |
---|---|
Format: | Article |
Language: | English |
Published: |
Budapest University of Technology
2014-06-01
|
Series: | eXPRESS Polymer Letters |
Subjects: | |
Online Access: | http://www.expresspolymlett.com/letolt.php?file=EPL-0005098&mi=cd |
id |
doaj-0b602a31f6cb4eb38b7886ed13616559 |
---|---|
record_format |
Article |
spelling |
doaj-0b602a31f6cb4eb38b7886ed136165592020-11-25T02:27:15ZengBudapest University of Technology eXPRESS Polymer Letters1788-618X2014-06-018642543510.3144/expresspolymlett.2014.46Study on the structure-properties relationship of natural rubber/SiO2 composites modified by a novel multi-functional rubber agentS. Y. YangL. LiuZ. X. JiaW. W. FuD. M. JiaY. F. LuoVulcanization property and structure-properties relationship of natural rubber (NR)/silica (SiO2) composites modified by a novel multi-functional rubber agent, N-phenyl- N'-(γ-triethoxysilane)-propyl thiourea (STU), are investigated in detail. Results from the infrared spectroscopy (IR) and X-ray photoelectron spectroscopy (XPS) show that STU can graft to the surface of SiO2 under heating, resulting in a fine-dispersed structure in the rubber matrix without the connectivity of SiO2 particles as revealed by transmission electron microscopy (TEM). This modification effect reduces the block vulcanization effect of SiO2 for NR/SiO2/STU compounds under vulcanization process evidently. The 400% modulus and tensile strength of NR/SiO2/STU composites are much higher than that of NR/SiO2/TU composites, although the crystal index at the stretching ratio of 4 and crosslinking densities of NR/SiO2 composites are almost the same at the same dosage of SiO2. Consequently, a structure-property relationship of NR/SiO2/STU composites is proposed that the silane chain of STU can entangle with NR molecular chains to form an interfacial region, which is in accordance with the experimental observations quite well.http://www.expresspolymlett.com/letolt.php?file=EPL-0005098&mi=cdRubbermulti-functional rubber agentstructure-property relationshisilica |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
S. Y. Yang L. Liu Z. X. Jia W. W. Fu D. M. Jia Y. F. Luo |
spellingShingle |
S. Y. Yang L. Liu Z. X. Jia W. W. Fu D. M. Jia Y. F. Luo Study on the structure-properties relationship of natural rubber/SiO2 composites modified by a novel multi-functional rubber agent eXPRESS Polymer Letters Rubber multi-functional rubber agent structure-property relationshi silica |
author_facet |
S. Y. Yang L. Liu Z. X. Jia W. W. Fu D. M. Jia Y. F. Luo |
author_sort |
S. Y. Yang |
title |
Study on the structure-properties relationship of natural rubber/SiO2 composites modified by a novel multi-functional rubber agent |
title_short |
Study on the structure-properties relationship of natural rubber/SiO2 composites modified by a novel multi-functional rubber agent |
title_full |
Study on the structure-properties relationship of natural rubber/SiO2 composites modified by a novel multi-functional rubber agent |
title_fullStr |
Study on the structure-properties relationship of natural rubber/SiO2 composites modified by a novel multi-functional rubber agent |
title_full_unstemmed |
Study on the structure-properties relationship of natural rubber/SiO2 composites modified by a novel multi-functional rubber agent |
title_sort |
study on the structure-properties relationship of natural rubber/sio2 composites modified by a novel multi-functional rubber agent |
publisher |
Budapest University of Technology |
series |
eXPRESS Polymer Letters |
issn |
1788-618X |
publishDate |
2014-06-01 |
description |
Vulcanization property and structure-properties relationship of natural rubber (NR)/silica (SiO2) composites modified by a novel multi-functional rubber agent, N-phenyl- N'-(γ-triethoxysilane)-propyl thiourea (STU), are investigated in detail. Results from the infrared spectroscopy (IR) and X-ray photoelectron spectroscopy (XPS) show that STU can graft to the surface of SiO2 under heating, resulting in a fine-dispersed structure in the rubber matrix without the connectivity of SiO2 particles as revealed by transmission electron microscopy (TEM). This modification effect reduces the block vulcanization effect of SiO2 for NR/SiO2/STU compounds under vulcanization process evidently. The 400% modulus and tensile strength of NR/SiO2/STU composites are much higher than that of NR/SiO2/TU composites, although the crystal index at the stretching ratio of 4 and crosslinking densities of NR/SiO2 composites are almost the same at the same dosage of SiO2. Consequently, a structure-property relationship of NR/SiO2/STU composites is proposed that the silane chain of STU can entangle with NR molecular chains to form an interfacial region, which is in accordance with the experimental observations quite well. |
topic |
Rubber multi-functional rubber agent structure-property relationshi silica |
url |
http://www.expresspolymlett.com/letolt.php?file=EPL-0005098&mi=cd |
work_keys_str_mv |
AT syyang studyonthestructurepropertiesrelationshipofnaturalrubbersio2compositesmodifiedbyanovelmultifunctionalrubberagent AT lliu studyonthestructurepropertiesrelationshipofnaturalrubbersio2compositesmodifiedbyanovelmultifunctionalrubberagent AT zxjia studyonthestructurepropertiesrelationshipofnaturalrubbersio2compositesmodifiedbyanovelmultifunctionalrubberagent AT wwfu studyonthestructurepropertiesrelationshipofnaturalrubbersio2compositesmodifiedbyanovelmultifunctionalrubberagent AT dmjia studyonthestructurepropertiesrelationshipofnaturalrubbersio2compositesmodifiedbyanovelmultifunctionalrubberagent AT yfluo studyonthestructurepropertiesrelationshipofnaturalrubbersio2compositesmodifiedbyanovelmultifunctionalrubberagent |
_version_ |
1724843278836170752 |