Nacre-bionic nanocomposite membrane for efficient in-plane dissipation heat harvest under high temperature
Waste heat management holds great promise to create a sustainable and energy-efficient society as well as contributes to the alleviation of global warming. Harvesting and converting this waste heat in order to improve the efficiency is a major challenge. Here we report biomimetic nacre-like hydroxyl...
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doaj-0b8237e0519f4c70bfbac165804c3cb32021-01-18T04:10:42ZengElsevierJournal of Materiomics2352-84782021-03-0172219225Nacre-bionic nanocomposite membrane for efficient in-plane dissipation heat harvest under high temperatureJiemin Wang0Dan Liu1Quanxiang Li2Cheng Chen3Zhiqiang Chen4Minoo Naebe5Pingan Song6David Portehault7Christopher J. Garvey8Dmitri Golberg9Weiwei Lei10Institute for Frontier Materials, Deakin University, Waurn Ponds Campus, Locked Bag 20000, Victoria, 3220, AustraliaInstitute for Frontier Materials, Deakin University, Waurn Ponds Campus, Locked Bag 20000, Victoria, 3220, Australia; Corresponding author.Institute for Frontier Materials, Deakin University, Waurn Ponds Campus, Locked Bag 20000, Victoria, 3220, AustraliaInstitute for Frontier Materials, Deakin University, Waurn Ponds Campus, Locked Bag 20000, Victoria, 3220, AustraliaInstitute for Frontier Materials, Deakin University, Waurn Ponds Campus, Locked Bag 20000, Victoria, 3220, AustraliaInstitute for Frontier Materials, Deakin University, Waurn Ponds Campus, Locked Bag 20000, Victoria, 3220, AustraliaCenter for Future Materials, University of Southern Queensland, Toowoomba, 4350, Australia; Corresponding author.Sorbonne Université, CNRS, Laboratoire de Chimie de La Matière Condensée de Paris (CMCP), 4 Place Jussieu, F-75005, Paris, FranceAustralia Nuclear Science and Technology Organization (ANSTO), Sydney, New South Wales, 2232, AustraliaCentre for Materials Science and School of Chemistry and Physics, Queensland University of Technology (QUT), Brisbane, QLD, 4001, AustraliaInstitute for Frontier Materials, Deakin University, Waurn Ponds Campus, Locked Bag 20000, Victoria, 3220, Australia; Corresponding author.Waste heat management holds great promise to create a sustainable and energy-efficient society as well as contributes to the alleviation of global warming. Harvesting and converting this waste heat in order to improve the efficiency is a major challenge. Here we report biomimetic nacre-like hydroxyl-functionalized boron nitride (BN)-polyimide (PI) nanocomposite membranes as efficient 2D in-plane heat conductor to dissipate and convert waste heat at high temperature. The hierarchically layered nanostructured membrane with oriented BN nanosheets gives rise to a very large anisotropy in heat transport properties, with a high in-plane thermal conductivity (TC) of 51 W m−1 K−1 at a temperature of ∼300 °C, 7314% higher than that of the pure polymer. The membrane also exhibits superior thermal stability and fire resistance, enabling its workability in a hot environment. In addition to cooling conventional exothermic electronics, the large TC enables the membrane as a thin and 2D anisotropic heat sink to generate a large temperature gradient in a thermoelectric module (ΔT = 23 °C) through effective heat diffusion on the cold side under 220 °C heating. The waste heat under high temperature is therefore efficiently harvested and converted to power electronics, thus saving more thermal energy by largely decreasing consumption.http://www.sciencedirect.com/science/article/pii/S2352847820301945Boron nitride nanosheetsNanocomposite membraneNacre-biomimeticHigh temperature heat spreaderIn-plane dissipation heat |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Jiemin Wang Dan Liu Quanxiang Li Cheng Chen Zhiqiang Chen Minoo Naebe Pingan Song David Portehault Christopher J. Garvey Dmitri Golberg Weiwei Lei |
spellingShingle |
Jiemin Wang Dan Liu Quanxiang Li Cheng Chen Zhiqiang Chen Minoo Naebe Pingan Song David Portehault Christopher J. Garvey Dmitri Golberg Weiwei Lei Nacre-bionic nanocomposite membrane for efficient in-plane dissipation heat harvest under high temperature Journal of Materiomics Boron nitride nanosheets Nanocomposite membrane Nacre-biomimetic High temperature heat spreader In-plane dissipation heat |
author_facet |
Jiemin Wang Dan Liu Quanxiang Li Cheng Chen Zhiqiang Chen Minoo Naebe Pingan Song David Portehault Christopher J. Garvey Dmitri Golberg Weiwei Lei |
author_sort |
Jiemin Wang |
title |
Nacre-bionic nanocomposite membrane for efficient in-plane dissipation heat harvest under high temperature |
title_short |
Nacre-bionic nanocomposite membrane for efficient in-plane dissipation heat harvest under high temperature |
title_full |
Nacre-bionic nanocomposite membrane for efficient in-plane dissipation heat harvest under high temperature |
title_fullStr |
Nacre-bionic nanocomposite membrane for efficient in-plane dissipation heat harvest under high temperature |
title_full_unstemmed |
Nacre-bionic nanocomposite membrane for efficient in-plane dissipation heat harvest under high temperature |
title_sort |
nacre-bionic nanocomposite membrane for efficient in-plane dissipation heat harvest under high temperature |
publisher |
Elsevier |
series |
Journal of Materiomics |
issn |
2352-8478 |
publishDate |
2021-03-01 |
description |
Waste heat management holds great promise to create a sustainable and energy-efficient society as well as contributes to the alleviation of global warming. Harvesting and converting this waste heat in order to improve the efficiency is a major challenge. Here we report biomimetic nacre-like hydroxyl-functionalized boron nitride (BN)-polyimide (PI) nanocomposite membranes as efficient 2D in-plane heat conductor to dissipate and convert waste heat at high temperature. The hierarchically layered nanostructured membrane with oriented BN nanosheets gives rise to a very large anisotropy in heat transport properties, with a high in-plane thermal conductivity (TC) of 51 W m−1 K−1 at a temperature of ∼300 °C, 7314% higher than that of the pure polymer. The membrane also exhibits superior thermal stability and fire resistance, enabling its workability in a hot environment. In addition to cooling conventional exothermic electronics, the large TC enables the membrane as a thin and 2D anisotropic heat sink to generate a large temperature gradient in a thermoelectric module (ΔT = 23 °C) through effective heat diffusion on the cold side under 220 °C heating. The waste heat under high temperature is therefore efficiently harvested and converted to power electronics, thus saving more thermal energy by largely decreasing consumption. |
topic |
Boron nitride nanosheets Nanocomposite membrane Nacre-biomimetic High temperature heat spreader In-plane dissipation heat |
url |
http://www.sciencedirect.com/science/article/pii/S2352847820301945 |
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