Single-Crystal-to-Single-Crystal Anion Exchange in a Gadolinium MOF: Incorporation of POMs and [AuCl4]−

Single-Crystal-to-Single-Crystal Anion Exchange in a Gadolinium MOF: Incorporation of POMs and [AuCl4]−

The encapsulation of functional molecules inside porous coordination polymers (also known as metal-organic frameworks, MOFs) has become of great interest in recent years at the field of multifunctional materials. In this article, we present a study of the effects of size and charge in the anion exch...

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Main Authors: Javier López-Cabrelles, Guillermo Mínguez Espallargas, Eugenio Coronado
Format: Article
Language:English
Published: MDPI AG 2016-04-01
Series:Polymers
Subjects:
MOFs
anion exchange
polyoxometalates
Online Access:http://www.mdpi.com/2073-4360/8/5/171
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spelling doaj-0bcc8807935448498361fde38eb4c8212020-11-25T01:03:52ZengMDPI AGPolymers2073-43602016-04-018517110.3390/polym8050171polym8050171Single-Crystal-to-Single-Crystal Anion Exchange in a Gadolinium MOF: Incorporation of POMs and [AuCl4]−Javier López-Cabrelles0Guillermo Mínguez Espallargas1Eugenio Coronado2Instituto de Ciencia Molecular (ICMol), Universidad de Valencia, c/Catedrático José Beltrán, 2, Paterna 46980, SpainInstituto de Ciencia Molecular (ICMol), Universidad de Valencia, c/Catedrático José Beltrán, 2, Paterna 46980, SpainInstituto de Ciencia Molecular (ICMol), Universidad de Valencia, c/Catedrático José Beltrán, 2, Paterna 46980, SpainThe encapsulation of functional molecules inside porous coordination polymers (also known as metal-organic frameworks, MOFs) has become of great interest in recent years at the field of multifunctional materials. In this article, we present a study of the effects of size and charge in the anion exchange process of a Gd based MOF, involving molecular species like polyoxometalates (POMs), and [AuCl4]−. This post-synthetic modification has been characterized by IR, EDAX, and single crystal diffraction, which have provided unequivocal evidence of the location of the anion molecules in the framework.http://www.mdpi.com/2073-4360/8/5/171MOFsanion exchangepolyoxometalates
collection DOAJ
language English
format Article
sources DOAJ
author Javier López-Cabrelles
Guillermo Mínguez Espallargas
Eugenio Coronado
spellingShingle Javier López-Cabrelles
Guillermo Mínguez Espallargas
Eugenio Coronado
Single-Crystal-to-Single-Crystal Anion Exchange in a Gadolinium MOF: Incorporation of POMs and [AuCl4]−
Polymers
MOFs
anion exchange
polyoxometalates
author_facet Javier López-Cabrelles
Guillermo Mínguez Espallargas
Eugenio Coronado
author_sort Javier López-Cabrelles
title Single-Crystal-to-Single-Crystal Anion Exchange in a Gadolinium MOF: Incorporation of POMs and [AuCl4]−
title_short Single-Crystal-to-Single-Crystal Anion Exchange in a Gadolinium MOF: Incorporation of POMs and [AuCl4]−
title_full Single-Crystal-to-Single-Crystal Anion Exchange in a Gadolinium MOF: Incorporation of POMs and [AuCl4]−
title_fullStr Single-Crystal-to-Single-Crystal Anion Exchange in a Gadolinium MOF: Incorporation of POMs and [AuCl4]−
title_full_unstemmed Single-Crystal-to-Single-Crystal Anion Exchange in a Gadolinium MOF: Incorporation of POMs and [AuCl4]−
title_sort single-crystal-to-single-crystal anion exchange in a gadolinium mof: incorporation of poms and [aucl4]−
publisher MDPI AG
series Polymers
issn 2073-4360
publishDate 2016-04-01
description The encapsulation of functional molecules inside porous coordination polymers (also known as metal-organic frameworks, MOFs) has become of great interest in recent years at the field of multifunctional materials. In this article, we present a study of the effects of size and charge in the anion exchange process of a Gd based MOF, involving molecular species like polyoxometalates (POMs), and [AuCl4]−. This post-synthetic modification has been characterized by IR, EDAX, and single crystal diffraction, which have provided unequivocal evidence of the location of the anion molecules in the framework.
topic MOFs
anion exchange
polyoxometalates
url http://www.mdpi.com/2073-4360/8/5/171
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AT guillermominguezespallargas singlecrystaltosinglecrystalanionexchangeinagadoliniummofincorporationofpomsandaucl4
AT eugeniocoronado singlecrystaltosinglecrystalanionexchangeinagadoliniummofincorporationofpomsandaucl4
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