High temperature properties improvement and microstructure regulation of Sm2Co17-based permanent magnet

It is well known that the high temperature magnetic properties of traditional Sm2Co17-based magnets can be further improved through adjustment of chemical composition and technique process. The Hcj of Sm(CobalFe0.1Cu0.09Zr0.03)z (z=7.0-7.3) magnets fluctuate over a large range at the variation of Sm...

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Main Authors: Chao Wang, Nengjun Yu, Minggang Zhu, Yikun Fang, Shuai Wang, Wei Li
Format: Article
Language:English
Published: AIP Publishing LLC 2019-12-01
Series:AIP Advances
Online Access:http://dx.doi.org/10.1063/1.5129687
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spelling doaj-0be2f3cd38184eaeac5d35359e1049a72020-11-25T01:54:56ZengAIP Publishing LLCAIP Advances2158-32262019-12-01912125237125237-710.1063/1.5129687High temperature properties improvement and microstructure regulation of Sm2Co17-based permanent magnetChao Wang0Nengjun Yu1Minggang Zhu2Yikun Fang3Shuai Wang4Wei Li5Division of Functional Materials, Central Iron and Steel Research Institute, Beijing 100081, ChinaDivision of Functional Materials, Central Iron and Steel Research Institute, Beijing 100081, ChinaDivision of Functional Materials, Central Iron and Steel Research Institute, Beijing 100081, ChinaDivision of Functional Materials, Central Iron and Steel Research Institute, Beijing 100081, ChinaDivision of Functional Materials, Central Iron and Steel Research Institute, Beijing 100081, ChinaDivision of Functional Materials, Central Iron and Steel Research Institute, Beijing 100081, ChinaIt is well known that the high temperature magnetic properties of traditional Sm2Co17-based magnets can be further improved through adjustment of chemical composition and technique process. The Hcj of Sm(CobalFe0.1Cu0.09Zr0.03)z (z=7.0-7.3) magnets fluctuate over a large range at the variation of Sm content, and Sm(CobalFe0.1Cu0.09Zr0.03)7.2 magnet shows excellent magnetic properties as (BH)max of 22.5 MGOe, Hcj of 28.3 kOe and Br of 9.65 kG at room temperature respectively. Meantime through optimization of solid solution conditions, the Sm(CobalFe0.1Cu0.09Zr0.03)7.2 magnets possess excellent magnetic properties as Br=7.22 kG, Hcj=7.6 kOe, (BH)max=11.6 MGOe at 500 °C. The β (temperature coefficient of coercivity from room temperature to 500°C) can be optimized to +0.1113%/°C from −0.134%/°C as quenching temperature increases from 420 °C to 830 °C, but Hcj deteriorates to 1.4 kOe from 28 kOe. Distribution of Cu content in cell boundaries for Sm(CobalFe0.1Cu0.09Zr0.03)7.2 quenched at 420 °C and 830 °C was analyzed using TEM-EDS, the result indicates that distribution of Cu is the main reason to give rise to the variation of Hcj and β.http://dx.doi.org/10.1063/1.5129687
collection DOAJ
language English
format Article
sources DOAJ
author Chao Wang
Nengjun Yu
Minggang Zhu
Yikun Fang
Shuai Wang
Wei Li
spellingShingle Chao Wang
Nengjun Yu
Minggang Zhu
Yikun Fang
Shuai Wang
Wei Li
High temperature properties improvement and microstructure regulation of Sm2Co17-based permanent magnet
AIP Advances
author_facet Chao Wang
Nengjun Yu
Minggang Zhu
Yikun Fang
Shuai Wang
Wei Li
author_sort Chao Wang
title High temperature properties improvement and microstructure regulation of Sm2Co17-based permanent magnet
title_short High temperature properties improvement and microstructure regulation of Sm2Co17-based permanent magnet
title_full High temperature properties improvement and microstructure regulation of Sm2Co17-based permanent magnet
title_fullStr High temperature properties improvement and microstructure regulation of Sm2Co17-based permanent magnet
title_full_unstemmed High temperature properties improvement and microstructure regulation of Sm2Co17-based permanent magnet
title_sort high temperature properties improvement and microstructure regulation of sm2co17-based permanent magnet
publisher AIP Publishing LLC
series AIP Advances
issn 2158-3226
publishDate 2019-12-01
description It is well known that the high temperature magnetic properties of traditional Sm2Co17-based magnets can be further improved through adjustment of chemical composition and technique process. The Hcj of Sm(CobalFe0.1Cu0.09Zr0.03)z (z=7.0-7.3) magnets fluctuate over a large range at the variation of Sm content, and Sm(CobalFe0.1Cu0.09Zr0.03)7.2 magnet shows excellent magnetic properties as (BH)max of 22.5 MGOe, Hcj of 28.3 kOe and Br of 9.65 kG at room temperature respectively. Meantime through optimization of solid solution conditions, the Sm(CobalFe0.1Cu0.09Zr0.03)7.2 magnets possess excellent magnetic properties as Br=7.22 kG, Hcj=7.6 kOe, (BH)max=11.6 MGOe at 500 °C. The β (temperature coefficient of coercivity from room temperature to 500°C) can be optimized to +0.1113%/°C from −0.134%/°C as quenching temperature increases from 420 °C to 830 °C, but Hcj deteriorates to 1.4 kOe from 28 kOe. Distribution of Cu content in cell boundaries for Sm(CobalFe0.1Cu0.09Zr0.03)7.2 quenched at 420 °C and 830 °C was analyzed using TEM-EDS, the result indicates that distribution of Cu is the main reason to give rise to the variation of Hcj and β.
url http://dx.doi.org/10.1063/1.5129687
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