The Reaction of 4,5-Dichloro-1,2,3-dithiazolium Chloride with Sulfimides: A New Synthesis of N-Aryl-1,2,3-dithiazolimines
N-Aryl-S,S-dimethylsulfimides 3(Ar = 4-NO2C6H4), 4 (Ar = Ph) and 5 (Ar = 4-Tol)react with Appel salt 1 to give the corresponding N-aryl-(4-chloro-5H-1,2,3-dithiazolylidene)benzenamines 8 (Ar = 4-NO2C6H4), 9 (Ar = Ph) and 10 (Ar = 4-Tol) in 84, 94 and 87% yields, respectively. The reaction proceeds i...
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MDPI AG
2009-07-01
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| Series: | Molecules |
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| Online Access: | http://www.mdpi.com/1420-3049/14/7/2356/ |
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doaj-0be334c438174239a71752177c05f7c32020-11-24T21:27:02ZengMDPI AGMolecules1420-30492009-07-011472356236210.3390/molecules14072356The Reaction of 4,5-Dichloro-1,2,3-dithiazolium Chloride with Sulfimides: A New Synthesis of N-Aryl-1,2,3-dithiazoliminesPanayiotis A. KoutentisAndreas S. KalogirouN-Aryl-S,S-dimethylsulfimides 3(Ar = 4-NO2C6H4), 4 (Ar = Ph) and 5 (Ar = 4-Tol)react with Appel salt 1 to give the corresponding N-aryl-(4-chloro-5H-1,2,3-dithiazolylidene)benzenamines 8 (Ar = 4-NO2C6H4), 9 (Ar = Ph) and 10 (Ar = 4-Tol) in 84, 94 and 87% yields, respectively. The reaction proceeds in the absence of base and a proposed reaction mechanism is given. http://www.mdpi.com/1420-3049/14/7/2356/dithiazoledithiazoliminesulfimidesulfilimineheteroareneappel salt |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Panayiotis A. Koutentis Andreas S. Kalogirou |
| spellingShingle |
Panayiotis A. Koutentis Andreas S. Kalogirou The Reaction of 4,5-Dichloro-1,2,3-dithiazolium Chloride with Sulfimides: A New Synthesis of N-Aryl-1,2,3-dithiazolimines Molecules dithiazole dithiazolimine sulfimide sulfilimine heteroarene appel salt |
| author_facet |
Panayiotis A. Koutentis Andreas S. Kalogirou |
| author_sort |
Panayiotis A. Koutentis |
| title |
The Reaction of 4,5-Dichloro-1,2,3-dithiazolium Chloride with Sulfimides: A New Synthesis of N-Aryl-1,2,3-dithiazolimines |
| title_short |
The Reaction of 4,5-Dichloro-1,2,3-dithiazolium Chloride with Sulfimides: A New Synthesis of N-Aryl-1,2,3-dithiazolimines |
| title_full |
The Reaction of 4,5-Dichloro-1,2,3-dithiazolium Chloride with Sulfimides: A New Synthesis of N-Aryl-1,2,3-dithiazolimines |
| title_fullStr |
The Reaction of 4,5-Dichloro-1,2,3-dithiazolium Chloride with Sulfimides: A New Synthesis of N-Aryl-1,2,3-dithiazolimines |
| title_full_unstemmed |
The Reaction of 4,5-Dichloro-1,2,3-dithiazolium Chloride with Sulfimides: A New Synthesis of N-Aryl-1,2,3-dithiazolimines |
| title_sort |
reaction of 4,5-dichloro-1,2,3-dithiazolium chloride with sulfimides: a new synthesis of n-aryl-1,2,3-dithiazolimines |
| publisher |
MDPI AG |
| series |
Molecules |
| issn |
1420-3049 |
| publishDate |
2009-07-01 |
| description |
N-Aryl-S,S-dimethylsulfimides 3(Ar = 4-NO2C6H4), 4 (Ar = Ph) and 5 (Ar = 4-Tol)react with Appel salt 1 to give the corresponding N-aryl-(4-chloro-5H-1,2,3-dithiazolylidene)benzenamines 8 (Ar = 4-NO2C6H4), 9 (Ar = Ph) and 10 (Ar = 4-Tol) in 84, 94 and 87% yields, respectively. The reaction proceeds in the absence of base and a proposed reaction mechanism is given. |
| topic |
dithiazole dithiazolimine sulfimide sulfilimine heteroarene appel salt |
| url |
http://www.mdpi.com/1420-3049/14/7/2356/ |
| work_keys_str_mv |
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