Di-μ-chlorido-bis({8-[bis(naphthalen-1-yl)phosphanyl]naphthalen-1-yl-κ2C1,P}palladium(II)) dichloromethane disolvate

Di-μ-chlorido-bis({8-[bis(naphthalen-1-yl)phosphanyl]naphthalen-1-yl-κ2C1,P}palladium(II)) dichloromethane disolvate

The title compound, [Pd2{P(C10H7)2(C10H6)}2Cl2]·2CH2Cl2, shows cyclometalation of one naphthalen-1-yl substituent of each of the phosphane ligands to the Pd dimer in a trans orientation; the complete dimer is generated by a centre of inversion. Two dichloromethane solvent molecules crea...

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Main Authors: Wade L. Davis, Alfred Muller
Format: Article
Language:English
Published: International Union of Crystallography 2012-12-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812048222
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spelling doaj-0bfcf8c6680b49c8b4f524f5f85a49d82020-11-24T21:25:46ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-12-016812m1565m156610.1107/S1600536812048222Di-μ-chlorido-bis({8-[bis(naphthalen-1-yl)phosphanyl]naphthalen-1-yl-κ2C1,P}palladium(II)) dichloromethane disolvateWade L. DavisAlfred MullerThe title compound, [Pd2{P(C10H7)2(C10H6)}2Cl2]·2CH2Cl2, shows cyclometalation of one naphthalen-1-yl substituent of each of the phosphane ligands to the Pd dimer in a trans orientation; the complete dimer is generated by a centre of inversion. Two dichloromethane solvent molecules create C—H...Cl interactions with the metal complex, generating supermolecular layers in the ab plane. Additional C—H...π and π–π [centroid–centroid distances = 3.713 (3), 3.850 (4) and 3.926 (3) Å] interactions join these planes into a three-dimensional supermolecular network.http://scripts.iucr.org/cgi-bin/paper?S1600536812048222
collection DOAJ
language English
format Article
sources DOAJ
author Wade L. Davis
Alfred Muller
spellingShingle Wade L. Davis
Alfred Muller
Di-μ-chlorido-bis({8-[bis(naphthalen-1-yl)phosphanyl]naphthalen-1-yl-κ2C1,P}palladium(II)) dichloromethane disolvate
Acta Crystallographica Section E
author_facet Wade L. Davis
Alfred Muller
author_sort Wade L. Davis
title Di-μ-chlorido-bis({8-[bis(naphthalen-1-yl)phosphanyl]naphthalen-1-yl-κ2C1,P}palladium(II)) dichloromethane disolvate
title_short Di-μ-chlorido-bis({8-[bis(naphthalen-1-yl)phosphanyl]naphthalen-1-yl-κ2C1,P}palladium(II)) dichloromethane disolvate
title_full Di-μ-chlorido-bis({8-[bis(naphthalen-1-yl)phosphanyl]naphthalen-1-yl-κ2C1,P}palladium(II)) dichloromethane disolvate
title_fullStr Di-μ-chlorido-bis({8-[bis(naphthalen-1-yl)phosphanyl]naphthalen-1-yl-κ2C1,P}palladium(II)) dichloromethane disolvate
title_full_unstemmed Di-μ-chlorido-bis({8-[bis(naphthalen-1-yl)phosphanyl]naphthalen-1-yl-κ2C1,P}palladium(II)) dichloromethane disolvate
title_sort di-μ-chlorido-bis({8-[bis(naphthalen-1-yl)phosphanyl]naphthalen-1-yl-κ2c1,p}palladium(ii)) dichloromethane disolvate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2012-12-01
description The title compound, [Pd2{P(C10H7)2(C10H6)}2Cl2]·2CH2Cl2, shows cyclometalation of one naphthalen-1-yl substituent of each of the phosphane ligands to the Pd dimer in a trans orientation; the complete dimer is generated by a centre of inversion. Two dichloromethane solvent molecules create C—H...Cl interactions with the metal complex, generating supermolecular layers in the ab plane. Additional C—H...π and π–π [centroid–centroid distances = 3.713 (3), 3.850 (4) and 3.926 (3) Å] interactions join these planes into a three-dimensional supermolecular network.
url http://scripts.iucr.org/cgi-bin/paper?S1600536812048222
work_keys_str_mv AT wadeldavis diamp956chloridobis8bisnaphthalen1ylphosphanylnaphthalen1ylamp9542c1ppalladiumiidichloromethanedisolvate
AT alfredmuller diamp956chloridobis8bisnaphthalen1ylphosphanylnaphthalen1ylamp9542c1ppalladiumiidichloromethanedisolvate
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